Opacity is an extinction cross-section per unit mass. It controls the photon mean free path and therefore the radiative temperature gradient in an optically thick star.
The Kramers opacity law has for bound-free and free-free absorption under its idealized ionized-gas assumptions.
Electron-scattering opacity is approximately independent of density and temperature in a fully ionized nonrelativistic plasma of fixed composition. For hydrogen mass fraction , .
Free-free opacity is absorption caused when a photon is absorbed during a Coulomb encounter between an electron and an ion. In the Kramers approximation its Rosseland mean scales approximately as .

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