Feynman diagrams organize the perturbative calculation of the matrix element in Fermi's golden rule. Each external line labels an incoming or outgoing particle state; each internal line contributes a propagator for a generally off-shell intermediate field; and each interaction vertex contributes a coupling and the appropriate spin, momentum and internal-symmetry structure. All indistinguishable allowed diagrams must be summed as probability amplitudes before taking the absolute square, so their interference contributes to the rate.
In the radiative pion decay diagram in part (b), solid arrowed lines are fermions; the wavy line joining the hadronic and leptonic vertices is a W boson propagator; and the wavy outgoing line is an external photon. Arrows track fermion number, so an outgoing antimuon has an arrow towards its production vertex. Each vertex conserves four-momentum; an internal propagator need not satisfy the on-shell energy–momentum relation. A closed loop Feynman diagram additionally requires an integration over an internal four-momentum.
The final Lorentz-invariant phase space, conservation Dirac delta functions, and the initial-state normalization or incident flux turn the squared scattering amplitude into a decay rate or cross section. A diagram supplies the dynamics; it is not itself the final density of states.
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