Let and denote neutral atomic rest masses for the appropriate parent and daughter, and initially neglect electronic binding energy corrections and daughter excitation. The Q values areFor beta-minus decay, the daughter nucleus has one extra positive charge. Its neutral atom contains one more electron than the neutral parent, cancelling the emitted electron's rest mass in the atomic accounting. For beta-plus decay, the neutral parent contains one more electron than the neutral daughter; together with the emitted Positron, this gives the subtraction. Thus beta-plus decay requires an atomic mass difference exceeding , whereas electron capture need not.
For electron capture, the captured bound electron is already included in . Capture from a shell leaving an atomic hole of excitation energy , and a nuclear excited state of energy , gives approximatelyThe hole's energy later appears as atomic radiation or Auger electrons. Subtract for either beta decay as well. Exact endpoints also depend on daughter ionization and small atomic binding energy changes; the boxed expressions are the conventional leading atomic-mass formulas.
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