The two processes are electron capture and beta-plus decay:
For neutral atomic masses, their available total energies obey
Hence electron capture has approximately more available energy. Electron-hole energies and nuclear recoil give smaller corrections for capture from a particular shell. With the physical mass difference, and the positron kinetic-energy budget is only about .
Electron capture dominates the argon-producing decays. Energetic advantage alone is not a universal theorem about branching fractions: electron density at the nucleus and nuclear transition matrix elements and selection rules also matter. In this case capture can populate the approximately excited argon level, whereas positron emission cannot; this is an additional reason the physical capture branch is much larger.[ref]

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