Put . Substitution of into the time-independent Schrödinger equation, followed by division by and multiplication by , separates the angular dependence:Thus andThe single-valued wavefunction condition, , requires . The regular boundary condition at the origin selects . Accordingly use in the radial ansatz; the printed notation describes the representatives.
For the two-dimensional Coulomb bound state, substitution of with the stipulated radial and energy scales givesThe coefficient of in the power series isThe regular solution otherwise has an exponentially growing contribution at large , incompatible with being normalizable. Termination at degree therefore requiresThe resulting is proportional to a Generalized Laguerre polynomial.
Define , the hydrogenic Rydberg energy for the stipulated mass. The first three distinct two-dimensional energies are , whereas in three dimensions they are . Both series approach zero from below, but the planar ground state is four times more tightly bound. Without spin the respective quantum degeneracies are and ; if individual degenerate states are counted, the second and third planar states already share the first excited energy. This comparison retains the supplied interaction; it does not replace it by the logarithmic electrostatic potential of a genuinely two-dimensional electromagnetic theory.
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