In the Hall effect, the Lorentz force deflects drifting charge carriers until a transverse electric field balances it: . Choose current along , field along and define . Since ,
The sign is negative for electrons with this convention. If the sample's mass density is and its molar mass is , the atomic number density is , so
Measure the transverse voltage, specimen thickness, current and magnetic field; reversing field and current helps remove longitudinal-voltage pickup and offsets. This free-electron count from a Hall coefficient assumes one approximately free carrier band. Multiple bands, unequal mobilities or a complicated Fermi surface can make a Hall coefficient differ from .

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