Past exam of the physics A course of the University of Cambridge / 2014 / Paper 2 / Section C / C11 / Solution

For two electrons per primitive cell,Set $A={\hslash }^2{\pi }^2/(2m_e{a}^2)=2.350\mathrm{eV}$. In the indirect gap in a uniformly split zone-boundary model approximation stipulated here, the free boundary energies are $A$ along $[10]$ at $X=(\pi /a,0)$ and $2A$ along $[11]$ at $M=(\pi /a,\pi /a)$. Opening a symmetric gap givesThe branches bend away from the free-electron crossings and flatten at their boundary extrema. Importantly, the upper band near $X$ lies below the lower band's corner energy:Therefore the crystal is metallic despite its positive boundary gaps; electron and hole occupations redistribute across overlapping bands. positive direct gaps can coexist with band overlap.

A microscopic square-lattice corner has additional plane-wave degeneracy. The quoted symmetric boundary numbers use the question's directional gap model, not an unspecified four-state corner Hamiltonian. For the indirect gap of a separable square cosine potential, a separable weak potential with the same face gap gives the lowest corner energy $2A-E_g=3.70\mathrm{eV}$, still above the $2.85\mathrm{eV}$ upper-band face energy. This refinement preserves the metallic conclusion.