For equally spaced illuminated slits, with , summing a geometric series of complex amplitudes gives
Here is the one-slit single-slit diffraction wave envelope. The grating equation for principal maxima is
with height and much weaker subsidiary maxima between orders. The first zeros around order are , so the angular distance from a maximum to its first minimum is, for large ,
Changing wavelength by moves the same diffraction order by
The Rayleigh criterion places the maximum for one wavelength at the first zero for its neighbour. Equating these separations gives
This is the ideal resolving power of a diffraction grating, for an illuminated and transmitted order with sufficiently narrow source and instrumental broadening. The zeroth order has no wavelength separation and therefore no useful spectral resolving power. The distinction between and the span of the outer slit centres is a small edge convention; the exact state count in the resolving-power formula is .
Figure 1.
Original diffraction grating pattern and the first-zero width used in the Rayleigh criterion
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