Past exam of the physics B course of the University of Cambridge / 2014 / Paper 1 / Section B / B6

Specifying potential on the complete boundary gives a Dirichlet boundary condition and a unique harmonic solution. Specifying its normal derivative gives a Neumann boundary condition, with the zero-net-flux compatibility condition and an undetermined additive constant. Mixed conditions on complementary portions also give uniqueness when a potential reference is fixed. In an exterior domain, conditions at infinity are needed. These statements follow by applying Green's first identity to the difference of two solutions. A metal in electrostatic equilibrium is an equipotential: $\Phi =V_0$, tangential electric field zero, and normal field $E_n=\sigma /{ϵ}_0$ just outside a vacuum interface.

For the conducting-wedge potential expansion, put $u=\Phi -V_0$ in the empty sector $0<\theta <\alpha$. For $u=r^{\nu }\Psi (\theta )$, Laplace's equation gives ${\Psi }^{\prime \prime }+{\nu }^2\Psi =0$. Vanishing values on both faces require $\Psi \propto \sin (n\pi \theta /\alpha )$, henceBounded potential at the corner sets $b_n=0$. The coefficients still require outer boundary data; the metal potential alone cannot select them. For a generic nonzero $a_1$, put $p=\pi /\alpha$. Differentiation givesIf $a_1=0$, the first nonzero higher harmonic replaces this leading term. For $\alpha =\pi /2$, $u\simeq 2a_{1}xy$, so $\mathbf{E}=-2a_1(y,x)$ and field lines satisfy $x^2-y^2=\mathrm{constant}$, meeting the metal faces normally and tending to zero field at the corner. For $\alpha =3\pi /2$, the electrostatic corner-field exponent is $-1/3$. A real tip's rounding cuts off this divergence; breakdown or field emission can limit the attainable field.