The angular momentum eigenstates have eigenvalue , where the angular momentum quantum number is . For each , the magnetic quantum number runs in unit steps from to . Here that magnetic quantum number is , so only half-integer are compatible:Integer cannot contain a eigenvalue . Applying the angular momentum lowering operator and using givesThe lowered vector is nonzero, since the adjoint operator identity givesFinally, is a self-adjoint operator, so its eigenstates for distinct eigenvalues are orthogonal. Explicitly,and hence .
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