Quantum theory course of the University of Oxford (A11)

Original solutions to past quantum theory examinations at the University of Oxford.

Solutions to all three questions of the University of Oxford Part A quantum theory paper, sat on 22 June 2023. Source: original released PDF, bundle pages 153–156; paper pages 1–4. Question statements are omitted. The symbol $\hslash$ denotes the reduced Planck constant.

The free particle has Hamiltonian operator $H=P^2/(2m)$, with momentum operator $P=-i\hslash {\partial }_x$. Its time-dependent Schrödinger equation isHere $x$ measures arc length for the particle on a circle, so the wavefunction normalization uses $dx$, rather than $d(x/R)$.

A stationary state has $\Psi (t,x)=e^{-iEt/\hslash }\psi (x)$. Substitution into the Schrödinger equation gives the energy eigenvalue equationThe trial wavefunction $C{e}^{ikx}$ satisfies it with $E={\hslash }^2{k}^2/(2m)$. The periodic boundary condition requires $e^{2\pi ikR}=1$, hence $k=n/R$, $n\in \mathbb{Z}$. The wavefunction normalization is $1=2\pi R|C{|}^2$, so a convenient common global phase gives the orthonormal basisIndeed, ${\int }_0^{2\pi R}{\varphi }_n^{\ast }{\varphi }_{q}dx={\delta }_{nq}$. This is the free particle spectrum on a circle. The ground state ${\varphi }_0$ has energy zero and is nondegenerate. Each positive energy level ${\hslash }^2{n}^2/(2m{R}^2)$, $n=1,2,\dots$, has energy eigenspace $\mathrm{span}\{{\varphi }_n,{\varphi }_{-n}\}$ and quantum degeneracy two. Real sine and cosine combinations give another basis of the same energy eigenspace.

Using ${\sin }^{2}u=\frac{1}{2}-\frac{1}{4}{e}^{2iu}-\frac{1}{4}{e}^{-2iu}$, the energy eigenstate decomposition isOnly the energy eigenvalues zero and $E_{\star }=2{\hslash }^2/(m{R}^2)$ occur. The last two terms are distinct momentum eigenstates in the same energy eigenspace.

The orthonormal basis makes the squared norm equal to the sum of squared expansion coefficients:Choose a positive real wavefunction normalization constant, fixing an irrelevant global phase:As a direct check, ${\int }_0^{2\pi R}{\sin }^4(x/R)dx=3\pi R/4$.

Under unitary time evolution, each energy eigenstate acquires its own dynamical phase. Since $E_2=E_{-2}=E_{\star }$, the wavefunction isAt $t=0$, the identity $1-\cos (2x/R)=2{\sin }^2(x/R)$ recovers the normalized initial wavefunction.

By the Born rule, the probability for a measured energy eigenvalue is the squared norm of the orthogonal projection onto its whole energy eigenspace. ThusEvery other energy eigenvalue has probability zero. These probabilities are independent of $T$: unitary time evolution under the unchanged Hamiltonian operator changes the dynamical phases but not the squared expansion coefficients. The two equal-energy terms describe one measurement outcome.

Let ${\Pi }_{\star }=|{\varphi }_2⟩⟨{\varphi }_2|+|{\varphi }_{-2}⟩⟨{\varphi }_{-2}|$ be the orthogonal projection for $E_{\star }$. The Lüders rule gives the normalized post-measurement stateThe factor $-e^{-i{E}_{\star }T/\hslash }$ is a global phase, so $\cos (2x/R)/\sqrt{\pi R}$ is an equivalent representative. The projective measurement preserves the quantum coherence between the two momentum eigenstates; it does not select one of them. This matters for the subsequent position probabilities.

Put $\tau =t-T$ and retain the global phase from the preceding Lüders rule update. Since $P{\varphi }_n=(\hslash n/R){\varphi }_n$, the same orthonormal basis diagonalizes the new Hamiltonian operator, withIn particular, ${\tilde{E}}_{\pm 2}=E_{\star }+m{s}^2/2\mp 2\hslash s/R$. Applying unitary time evolution from $T$ therefore givesThis is rigid translation from a momentum term in the Hamiltonian: the position probability density moves with velocity $-s$. The plus sign in $x+s\tau$ follows directly from the negative sign of $-sP$. At $\tau =0$ the expression agrees exactly with the preceding post-measurement state.

For an arc represented by $0\le x\le a$, take $0\le a\le 2\pi R$. The Born rule usesIntegrate using ${\cos }^{2}u=(1+\cos 2u)/2$:The result is zero at $a=0$ and one at $a=2\pi R$, checking the wavefunction normalization. At $s=0$ it reduces to $a/(2\pi R)+\sin (4a/R)/(8\pi )$, the stationary position probability. Longer intervals on the periodically identified coordinate require specifying the corresponding subset of the circle; integrating multiple turns would count the same positions repeatedly.

The Hamiltonian operator separates into two commuting one-dimensional quantum harmonic oscillators. WriteProducts of harmonic oscillator eigenfunctions giveHere $H_n$ is the physicists' Hermite polynomial, so $H_0=1$, $H_1(u)=2u$ and $H_2(u)=4u^2-2$. The first six energy eigenstates, ordered with multiplicity, areFor this two-dimensional oscillator level ordering, the excitation energies obeyEvery state with $n_1+n_2\ge 3$ costs at least $3\hslash {\omega }_1$, so none has been missed. Equalities within the list occur when ${\omega }_2={\omega }_1=\omega$. Then the two-dimensional isotropic harmonic oscillator hasThe quantum degeneracy counts $n_1=0,\dots ,N$ with $n_2=N-n_1$. The six listed states occupy three distinct energy levels, of quantum degeneracies one, two and three.

Since $X$ and $P$ are self-adjoint operators, the adjoint operator relation requires $c_{+}=c_{-}=c$ and $d_{+}=-d_{-}=-d$. Thus $a_{-}=cX+idP$ and $a_{+}=cX-idP$. The canonical commutation relation $[X,P]=i\hslash I$ givesMatching the $X^2$, $P^2$ and identity operator coefficients in $H=\hslash \omega (a_{+}{a}_{-}+\lambda I)$ yieldsConsequently all real solutions areThe conventional creation and annihilation operators use $\epsilon =1$. The other choice multiplies both by minus one and satisfies all the given equations. This harmless freedom is the oscillator ladder-operator sign convention; the subsequent formulas use the positive choice in both coordinates.

Use the canonical commutation relationsWriting $c_j=\sqrt{m{\omega }_j/(2\hslash )}$, $d_j=1/\sqrt{2m\hslash {\omega }_j}$, direct expansion of the commutator givesThe Fock vacuum ${\psi }_{0,0}$ is annihilated by both $a_{j,-}$. Successive creation operators generateHence, in the order of part (a), the six energy eigenstates are proportional toIf the Fock vacuum has unit norm, dividing the general expression by $\sqrt{n_1!n_2!}$ gives normalized number states. Normalization is not required here, but using this convention makes the later change of basis unambiguous.

The orbital angular momentum $L_3=X_1{P}_2-X_2{P}_1$ generates rotations in the plane. The canonical commutation relations giveUse the commutator product rule $[A,B^2]=[A,B]B+B[A,B]$. Since different coordinates commute,Thus, for arbitrary positive angular frequencies,At ${\omega }_1={\omega }_2$, this becomes $\boxed{[L_3,H]=0}$. The rotational symmetry of the two-dimensional isotropic harmonic oscillator allows a basis of simultaneous energy eigenstates and orbital angular momentum eigenstates.

Set ${\omega }_1={\omega }_2=\omega$. Inverting the creation and annihilation operators givesSubstitute these expressions in $L_3=X_1{P}_2-X_2{P}_1$. Terms with two creation operators or two annihilation operators cancel because different modes commute. The remaining orbital angular momentum in oscillator ladder operators isEquivalently it is $-i\hslash (a_{1,+}{a}_{2,-}-a_{2,+}{a}_{1,-})$, consistent with the circular ladder operators of a two-dimensional oscillator.

Choose the first three energy eigenstates consistently as ${\psi }_{0,0}$, ${\psi }_{1,0}=a_{1,+}{\psi }_{0,0}$ and ${\psi }_{0,1}=a_{2,+}{\psi }_{0,0}$. The Fock vacuum is annihilated by both lowering operators, soFor example $a_{1,-}{a}_{1,+}{\psi }_{0,0}={\psi }_{0,0}$, while $a_{2,-}{\psi }_{1,0}=0$, giving the middle formula. Thus the simultaneous eigenstates can be chosen asTheir pairs of eigenvalues $(H,L_3)$ are respectively $(\hslash \omega ,0)$, $(2\hslash \omega ,+\hslash )$ and $(2\hslash \omega ,-\hslash )$. The factor $1/\sqrt{2}$ normalizes the combinations when the original three states are normalized. Mixing only inside the degenerate first-excited energy eigenspace preserves the energy eigenvalue while diagonalizing $L_3$.

Write $\alpha =m\omega /\hslash$. The first Hermite polynomials give ${\psi }_{0,0}\propto e^{-\alpha (x_1^2+x_2^2)/2}$ and ${\psi }_{1,0},{\psi }_{0,1}$ proportional, with the same constant, to $x_1{e}^{-\alpha (x_1^2+x_2^2)/2}$ and $x_2{e}^{-\alpha (x_1^2+x_2^2)/2}$. Thus in Cartesian coordinates the new wavefunctions areUsing polar coordinates $x_1=r\cos \phi$, $x_2=r\sin \phi$ givesThe orbital angular momentum is $L_3=-i\hslash {\partial }_{\phi }$, which immediately verifies its eigenvalues $0,\pm \hslash$. Multiplying these spatial wavefunctions by $e^{-i\omega t}$ for ${\chi }_0$ and $e^{-2i\omega t}$ for ${\chi }_{\pm }$ gives the corresponding full stationary states.

The angular momentum commutation relations arewhere ${\epsilon }_{ijk}$ is the Levi-Civita symbol. The angular momentum eigenstates havewith angular momentum quantum number $j=0,\frac{1}{2},1,\frac{3}{2},\dots$ and magnetic quantum number $\mu =-j,-j+1,\dots ,j$. There are $2j+1$ such states in one irreducible spin representation, so the $J^2$ eigenspace has dimension $2j+1$ within that multiplet. The use of $\mu$ avoids confusing the magnetic quantum number with the particle mass in the earlier questions.

For completeness, the ladder operators $J_{\pm }=J_1\pm i{J}_2$ satisfy $[J_3,J_{\pm }]=\pm \hslash J_{\pm }$ andThe upper and lower ends are $\mu =\pm j$; integer steps between them require $2j$ to be a nonnegative integer. This explains both the spectrum and the multiplet dimension. Pure orbital angular momentum permits only integer $j$, whereas general spin allows half-integers. If a larger Hilbert space contains several copies of the same irreducible spin representation, the full $J^2$ eigenspace includes all those copies: its dimension is $(2j+1)$ times their multiplicity, and can be infinite. The paper's dimension question is understood per irreducible multiplet.

In the ordered orthonormal basis $(|\frac{1}{2},\frac{1}{2}⟩,|\frac{1}{2},-\frac{1}{2}⟩)$, the spin one-half angular momentum operators are $J_i=(\hslash /2){\sigma }_i$, with Pauli matricesThe ladder operators areExplicit multiplication gives $J_{+}{J}_{-}={\hslash }^2\mathrm{diag}(1,0)$ and $J_{-}{J}_{+}={\hslash }^2\mathrm{diag}(0,1)$. Their commutator is therefore

Choose the ordered angular momentum eigenstates $(|1,1⟩,|1,0⟩,|1,-1⟩)$, so $J_3=\hslash \mathrm{diag}(1,0,-1)$. Since $[J_3,J_{\pm }]=\pm \hslash J_{\pm }$, a nonzero matrix element of $J_{+}$ must increase the magnetic quantum number by one, and one of $J_{-}$ must decrease it by one. Thus only entries $(1,2),(2,3)$ of $J_{+}$ and $(2,1),(3,2)$ of $J_{-}$ can be nonzero. The adjoint operator identity $J_{-}=J_{+}^{†}$ givesFor the $j=1$ irreducible spin representation, both adjacent transitions are present; the following calculation determines their sizes.

The phases of the three basis vectors can be chosen so that $A$ and $B$ are nonnegative real numbers. Matrix multiplication then givesThe angular momentum commutation relations require this to equal $2\hslash J_3=2{\hslash }^2\mathrm{diag}(1,0,-1)$. Equating diagonal entries yieldsHenceThese are also the $j=1$ special case of the normalized spin ladder operator coefficients $\hslash \sqrt{j(j+1)-\mu (\mu \pm 1)}$.

Recover the angular momentum operators from $J_1=(J_{+}+J_{-})/2$ and $J_2=(J_{+}-J_{-})/(2i)$. The spin-one angular momentum matrices in the chosen descending-$J_3$ orthonormal basis areThey are self-adjoint operators, satisfy $[J_i,J_j]=i\hslash {\epsilon }_{ijk}{J}_k$, and give $J^2=2{\hslash }^{2}I$, as required for $j=1$.

The Hamiltonian operator $H=\omega J_3$ is already diagonal in the angular momentum eigenstate basis of part (b). Its three distinct energy eigenvalues and stationary states areThus the three column eigenvectors are $(1,0,0{)}^{\mathsf{T}}$, $(0,1,0{)}^{\mathsf{T}}$ and $(0,0,1{)}^{\mathsf{T}}$, with energies $+\hslash \omega$, zero and $-\hslash \omega$, respectively. Each is nondegenerate since $\omega >0$. Any nonzero scalar multiple gives the same stationary state after normalization; a quantum superposition of different energies is generally not stationary.

Diagonalizing the $J_1$ matrix gives the normalized eigenvectorswith eigenvalues $+\hslash ,0,-\hslash$, respectively. The first projective measurement prepares $v_{+}$ up to global phase, regardless of the earlier state, conditional on obtaining $+\hslash$.

The unitary time evolution under $H=\omega J_3$ gives, with $\theta =\omega t$,The probability amplitudes for the second projective measurement areThe Born rule therefore gives the general spin-one transverse measurement after axial precession:At the specified times $t_k=\pi k/\omega$, $\theta =\pi k$, soFor even $k$, the result is certainly $+\hslash$; for odd $k$, it is certainly $-\hslash$. Although zero belongs to the spectrum of the observable, it never occurs at these times. Indeed, for even $k$ the evolved vector is $v_{+}$, while for odd $k$ it is $-v_{-}$, where the minus sign is a global phase.

Solutions to all three questions of the University of Oxford Part A quantum theory paper, sat on 16 June 2021. Source: original released PDF, bundle pages 145–148; paper pages 1–4. The symbol $\hslash$ denotes the reduced Planck constant. All four measurement experiments in question 1(c) start independently from the wavefunction in question 1(b).

For a free particle, the Hamiltonian operator is $H=P^2/(2m)$, where $P=-i\hslash d/dx$ is the momentum operator. The time-independent Schrödinger equation is thereforeThe full stationary state is $\Psi (x,t)=e^{-iEt/\hslash }\psi (x)$. The periodic boundary condition identifies $x$ and $x+2\pi$, giving a particle on a circle with wavefunction normalization over one period.