For a unit mass of ideal gas, . Since depends only on temperature, , giving . For a dry parcel in adiabatic, quasistatic ascent, the first law of thermodynamics is . Environmental hydrostatic equilibrium gives , so a convectively well-mixed layer has the dry adiabatic lapse rate
This assumes negligible condensation, approximately constant , well-mixed composition and efficient convection; a radiative or stably stratified layer need not follow it. For mole fractions and molar masses , and . Molecular vibrational excitation can make depend on temperature; then . Nitrogen dominance near terrestrial temperatures gives the familiar order .

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