For a unit mass of ideal gas, h=u+P/ρ=u+RaT. Since u depends only on temperature, cp=dh/dT=cv+Ra, giving Ra=cp−cv. For a dry parcel in adiabatic, quasistatic ascent, the first law of thermodynamics is cpdT=ρ−1dP. Environmental hydrostatic equilibrium gives dP/dz=−ρg, so a convectively well-mixed layer has the dry adiabatic lapse rateThis assumes negligible condensation, approximately constant g, well-mixed composition and efficient convection; a radiative or stably stratified layer need not follow it. For mole fractions xN,xC and molar masses MN,MC, Ra=R/(xNMN+xCMC) and cp=[xNCp,N+xCCp,C]/(xNMN+xCMC). Molecular vibrational excitation can make cp depend on temperature; then Γd=g/cp(T). Nitrogen dominance near terrestrial temperatures gives the familiar order 10Kkm−1.
Γd=−dzdT=cpg.
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