Assume dilute, nondegenerate ideal electrons, protons and neutral atoms in thermal and chemical equilibrium, with charge neutrality np=ne. Set μH=μp+μe, using each ideal species' translational factor nλth3/g and hydrogen ground-state binding energy −R. Neglect excited states and take the heavy proton/atom thermal-wavelength ratio as one. With electron spin and neutral-atom degeneracies treated in the convention of the source, the remaining factor isDifferent partition-degeneracy conventions must be propagated consistently. Screening, dense-plasma level dissolution and departures from local thermodynamic equilibrium lie outside this derivation.
nHne2=(h22πmekBT)3/2e−R/(kBT).
For total nuclear density n, ne=nζ and nH=n(1−ζ). Saha's equation becomes nζ2/(1−ζ)=CT3/2e−R/(kBT). At ζ≪1,The factor two in the exponent follows from taking a square root; using the full ionization temperature would double the predicted logarithmic slope.
ζ≃C/nT3/4e−TH/T,m=43,TH=2kBR≃7.89×104 K.
Write u=1/T. Then logζ=constant−(3/4)logu−THu, giving local slope dlog10ζ/du=−(TH+3T/4)/log10. At 5000–6000 K its magnitude is about 3.6×104 K. The low-ionization tail in the original graph drops roughly one decade per 2.8×10−5 K−1, consistent with this value.
At u=2.0×10−4 K−1, the graph gives T≃5000 K and ζ≃0.004. Invert the full equation to get n=CT3/2e−R/(kBT)(1−ζ)/ζ2, yielding n∼1018 m−3. The neighboring tail markers give the same order; plotting precision and the squared dependence on the read ionization fraction preclude claiming many significant digits.
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