A sudden wall displacement leaves the initial wavefunction unchanged: it is 2/Lsin(πx/L) on [0,L] and zero on (L,2L]. It is not an eigenfunction of the new Hamiltonian, so there is no single certain new energy. Its energy expectation immediately afterward remains E1old, as seen from ℏ2∫∣ψ′∣2/(2m); the measurement outcomes are Ennew=n2E1old/4.
The new ground state is L−1/2sin(πx/(2L)). Its overlap is 42/(3π), soThe discontinuity of the derivative at the former wall does not invalidate the finite quadratic-form expectation, although it matters when applying the differential Hamiltonian pointwise. Adiabatic expansion would instead keep the state in the ground level and reduce its energy by four.
Pnew ground=9π232≃0.360.
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