Use and define the total four-momentum . For an inertial frame moving with velocity relative to the laboratory, the Lorentz boost gives
Choose parallel to and require zero total three-momentum. Then
This requires , so that the total four-momentum is timelike. Its invariant mass is , the total relativistic energy in the center-of-momentum frame. If all particles are exactly parallel photons, the total four-momentum is null and no finite-velocity center-of-momentum frame exists.
Sign qualification. The minus sign printed in the source describes the laboratory's velocity in the center-of-momentum frame, or the parameter of an active Lorentz boost with a plus-sign spatial rule. It is not the velocity of the center-of-momentum frame relative to the laboratory under question 1's passive convention. For example, a single particle with has its rest frame moving at . The printed would give , which is not zero. This explicitly resolves the sign rather than assigning a rest frame moving away from the particle.

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