Past exam of the thermal and statistical physics course of the University of Cambridge / 2016 / Paper 1 / 2 / c

Landau theory expands the free energy in a small order parameter and keeps terms allowed by the system's symmetries. For a scalar order parameter $q$ with sign-reversal symmetry in Landau theory $q\mapsto -q$, a useful free-energy density isAt zero conjugate field $h$, the quartic Landau equilibrium branches obtained by minimizing areThe single minimum becomes two symmetry-related minima: the order parameter turns on continuously and a chosen equilibrium phase spontaneously breaks the symmetry. At the critical temperature the quadratic restoring term vanishes. The mean-field exponent is $q\propto (T_c-T{)}^{1/2}$; the susceptibility above $T_c$ is $\partial q/\partial h=1/[a(T-T_c)]$.

More general allowed terms describe other transitions. A negative quartic term, stabilized by a positive sixth-order term, can give a first-order transition with a discontinuous order parameter and metastable minima. Without the sign-reversal symmetry, a cubic term may also be allowed. The expansion is phenomenological: its coefficients depend on microscopic physics. Minimizing a uniform polynomial neglects important spatial fluctuations, particularly near a critical point, so its critical exponents need not be exact.^[ref]