Photoconductor transient with quadratic recombination

A photoconductor transient with quadratic recombination is a carrier-density model in which the loss rate grows as the square of the mobile excess density. It explains how nonlinear loss can produce different turn-on and turn-off waveforms without assigning unrelated exponential lifetimes to the two directions. A photoconductor converts illumination-dependent electrical conductivity into a signal under external bias; the manufacturer's primary PbS description establishes that conversion mechanism.^[ref] The quadratic loss law below is an explicitly stipulated model, not a fitted specification of that detector.

Assume a spatially uniform excess density $n\ge 0$, generation rate $g\ge 0$, constant coefficient $\beta >0$ and an output proportional to $n$ at fixed mobility and bias:Density has units ${\mathrm{m}}^{-3}$, $g$ has units ${\mathrm{m}}^{-3}{\mathrm{s}}^{-1}$ and $\beta$ has units ${\mathrm{m}}^3/s$. A two-carrier recombination rate proportional to the product of equal electron and hole densities motivates a quadratic term in an appropriate regime. Background carriers, other loss processes, contacts and trapping can invalidate that specialization.

For constant $g>0$, set $n_{\infty }=\sqrt{g/\beta }$ and $k=\beta n_{\infty }$. Separating variables, or differentiating the following expression, gives the solution for any finite nonnegative initial density $n_0$:For $n_0=0$ it reduces to $n_{\infty }\tanh (kt)$. For $n_0=n_{\infty }$ it stays at equilibrium, and for $n_0>n_{\infty }$ it approaches the same equilibrium from above. In the dark, $g=0$ instead yieldsThe reciprocal-density plot is linear in this model, while a semilogarithmic decay plot is curved. The dark half-decay time is $1/(\beta n_0)$, so it depends on the starting illumination.

The small-signal lifetime under quadratic recombination is different again. Linearize about a nonzero background $\overline{n}=\sqrt{\overline{g}/\beta }$:A locally exponential small-signal response can therefore coexist with a strongly nonexponential large dark transient. One measured time constant cannot be substituted for all three quantities.

For an original example, stipulate $\beta =10^{-15}{\mathrm{m}}^3/s$ and $\overline{n}=10^{18}{\mathrm{m}}^{-3}$. Then $\overline{g}=10^{21}{\mathrm{m}}^{-3}{\mathrm{s}}^{-1}$, dark half-decay time $1\mathrm{ms}$, small-signal lifetime $0.5\mathrm{ms}$ and small-signal half-power frequency about $318.3\mathrm{Hz}$. Four times the background generation doubles equilibrium density and doubles that frequency in this model.

A proposed test measures small modulation about several backgrounds separately from complete turn-off traces, while controlling actual detector bias, temperature and readout response. Examine reciprocal-density linearity only after justifying how the measured current maps to density. A successful fit supports the tested rate-law approximation; it does not uniquely identify the microscopic electron-hole recombination mechanism. Temperature and spectral sensitivity also vary in real PbS detectors and must be held or measured independently.^[ref]