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The first step of the proton–proton chain isHere $d$ is the deuteron. A weak charged current converts one proton into a neutron, while the resulting proton–neutron pair becomes bound. The Q value follows from the difference of initial and final rest energies:This includes the emitted Positron's rest energy in the final-state mass and excludes its subsequent electron-positron annihilation. The nuclear binding energy of the deuteron makes this reaction possible although the isolated conversion $p\to n+e^{+}+{\nu }_e$ is energetically forbidden. The released energy is shared by final-state kinetic energies, including the escaping neutrino.

The bookkeeping reaction isBoth mass number and electric charge are conserved: $236=92+140+4$ and $92=37+55$. Express each atomic mass as the sum of its constituent rest masses minus its nuclear binding energy. The total constituent masses, including the atomic-electron masses, cancel between the two sides. Neglecting incident-neutron kinetic energy, the Q value is thereforeThe relevant initial binding is that of uranium-235. Introducing uranium-236 as an intermediate state is possible only if the neutron-capture energy is also accounted for.

In the stated coefficient convention,Uranium-235 has odd $A$, hence ${\delta }_B=0$. Both products are odd–odd: rubidium has $(Z,N)=(37,55)$ and caesium has $(55,85)$. Each therefore has ${\delta }_B=-12/\sqrt{A}$ MeV. Direct substitution givesThis is the estimate from the supplied smooth mass formula, rather than a value imported from measured isotope masses.

For $100$ MW recovered as the stated fission energy, the annual energy output is $10^8(365.25)(86400)$ J. ThusEach event consumes one uranium-235 atom. With Avogadro constant $N_A=6.02214076\times 10^{23}$ mol${}^{-1}$ and molar mass approximated as $235$ g mol${}^{-1}$,This uses the stated power directly as recovered fission power; an unspecified conversion efficiency or additional heat-loss correction cannot be inferred from it.

The Q value of a reaction or particle decay is the initial total rest energy minus the final total rest energy. Positive $Q$ releases kinetic energy; a negative $Q$ requires energy supplied by incident motion or another source. Atomic and bare nuclear mass conventions must be distinguished when counting electrons in beta decay.

Beta decay Q values depend on small differences between much larger atomic masses. A smooth semi-empirical mass formula can therefore approximate absolute masses reasonably while predicting the wrong sign for a MeV-scale decay threshold. Nuclear pairing explains offset even-even and odd-odd mass branches, but does not guarantee that every specific even-even neighbor lies below the intervening odd-odd nucleus. Measured masses or additional nuclear shell corrections are needed for quantitative threshold tests near a model's residual error scale.