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A representative Feynman diagram annihilates $u\bar{d}$ into $W^{+\ast }$, producing ${\nu }_{\mu }$ and an off-shell ${\mu }^{+}$; the charged antilepton emits a photon and becomes the outgoing ${\mu }^{+}$. The top panel below shows this contribution. A complete gauge-invariant decay amplitude includes radiation from the charged hadronic side, together with structure-dependent terms. The physical separation into inner bremsstrahlung, structure-dependent radiation, and their interference is explicit in the standard radiative pion decay description.^[ref]

Here is an explicit finite model of phase space alone, with its assumptions exposed. Neglect the neutrino mass, treat the photon as massless, and replace the spin-summed invariant decay amplitudes by constants over the available Lorentz-invariant phase space. Write $M=m_{\pi }$, $m=m_{\mu }$, $r=m^2/M^2$, and use natural units. The three-body phase space with one massive daughter follows by factoring through an intermediate invariant squared mass $s$:The two-body comparison has ${\Phi }_2(M;m,0)=(1-r)/(8\pi )$. Since ${\Gamma }_n=\overline{|{\mathcal{M}}_n{|}^2}{\Phi }_n/(2M)$, assuming $\overline{|{\mathcal{M}}_3{|}^2}/\overline{|{\mathcal{M}}_2{|}^2}=\kappa e^2/M^2$ givesHere $\kappa$ is a dimensionless constant encapsulating the assumed matrix element ratio, and ${\alpha }_{\mathrm{em}}$ is the fine-structure constant. If the two-body mode dominates, this ratio approximates the radiative branching fraction. Near $m=M$, $1-r^2+2r\ln r=(1-r{)}^3/3+O((1-r{)}^4)$, displaying the extra phase space suppression.

This model is not a prediction of a physical uncut radiative branching fraction. Actual inner bremsstrahlung has a soft-photon singularity, so a count of events with a separately observed photon requires a positive photon energy cut. To see both the missing input and the mass dependence explicitly, the leading soft-photon result for $E_{\mathrm{cut}}<E_{\gamma }<E_{\mathrm{soft}}\ll E_{\max }$ isThe coefficient follows from the radiation factor $e[p_{\mu }\cdot ϵ/(p_{\mu }\cdot k)-p_{\pi }\cdot ϵ/(p_{\pi }\cdot k)]$: angular integration gives ${\beta }^{-1}\ln [(1+\beta )/(1-\beta )]-2$, where $\beta =(1-r)/(1+r)$, and the soft energy integral is $\int d{E}_{\gamma }/E_{\gamma }$. Thus a finite physical number cannot be deduced from the two masses and phase space alone. The infrared divergence cancels only when the corresponding unresolved real radiation and virtual radiative corrections are combined in an inclusive observable.

Feynman diagrams organize the perturbative calculation of the matrix element in Fermi's golden rule. Each external line labels an incoming or outgoing particle state; each internal line contributes a propagator for a generally off-shell intermediate field; and each interaction vertex contributes a coupling and the appropriate spin, momentum and internal-symmetry structure. All indistinguishable allowed diagrams must be summed as probability amplitudes before taking the absolute square, so their interference contributes to the rate.

In the radiative pion decay diagram in part (b), solid arrowed lines are fermions; the wavy line joining the hadronic and leptonic vertices is a W boson propagator; and the wavy outgoing line is an external photon. Arrows track fermion number, so an outgoing antimuon has an arrow towards its production vertex. Each vertex conserves four-momentum; an internal propagator need not satisfy the on-shell energy–momentum relation. A closed loop Feynman diagram additionally requires an integration over an internal four-momentum.

The final Lorentz-invariant phase space, conservation Dirac delta functions, and the initial-state normalization or incident flux turn the squared scattering amplitude into a decay rate or cross section. A diagram supplies the dynamics; it is not itself the final density of states.

Section 62.1 distinguishes inner bremsstrahlung from structure-dependent radiative pion decay and their interference. Equations (62.3)–(62.4) give the double differential decay width in terms of the scaled photon and charged-lepton energies and the squared lepton-to-meson mass ratio.