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Both Thomson scattering and Rayleigh scattering can be understood as radiation from a dipole driven by the incident electric field. Their different frequency dependences come from the response of a free charge compared with a bound charge.

For a free particle of charge $q$ and mass $m$, a harmonic field gives $m\ddot{\mathbf{x}}=q\mathbf{E}$, hence $\mathbf{p}=q\mathbf{x}=-q^2\mathbf{E}/(m{\omega }^2)$. The radiated field contains two time derivatives of $\mathbf{p}$, cancelling the response's ${\omega }^{-2}$. The Thomson cross section is consequently independent of frequency in the classical low-recoil regime:For incident linear polarization with unit polarization $\mathbf{ϵ}$, summing over outgoing polarizations gives $d\sigma /d\Omega =r_q^2[1-|\hat{\mathbf{n}}\cdot \mathbf{ϵ}{|}^2]$. Radiation vanishes along the acceleration and is strongest perpendicular to it. Averaging an incident unpolarized light beam giveswhere $\Theta$ is the scattering angle. Scattering through $90^{\circ }$ is fully linearly polarized perpendicular to the scattering plane for this ideal isotropic dipole model. The electron case dominates over equally charged heavier particles because the cross section scales as $m^{-2}$. recoil corrections become necessary when photon energy is no longer small compared with $m{c}^2$.

For a bound charge with natural frequency ${\omega }_0$ and damping rate ${\gamma }_d$,Far below resonance, ${\alpha }_{\mathrm{e}}$ is approximately constant, soThis is Rayleigh scattering. It requires a scatterer small compared with the wavelength and, for the simple expression, an isotropic linear dipole response. Atoms, molecules and small dielectric particles provide examples. The stronger scattering of shorter visible wavelengths explains blue skylight; absorption and the nonuniform solar spectrum prevent treating that simple scaling as a complete color calculation.^[ref]

For isotropic electric scatterers the normalized angular and polarization patterns are the same as in Thomson scattering. The frequency scaling distinguishes their limits: a free charge has a displacement proportional to ${\omega }^{-2}$, whereas a tightly bound charge has an approximately frequency-independent displacement. Near resonance, far outside the small-particle limit, or with anisotropic polarizability, the simple Rayleigh formula must be modified. In particular, the electric-only pattern must not silently be applied to a perfectly conducting sphere whose magnetic dipole response is also retained.

A scattering measurement should subtract stray-light and detector backgrounds, control scatterer density and optical thickness, and calibrate detector response and incident power when comparing wavelengths. A polarization analyzer at $90^{\circ }$ tests the dipole pattern; multiple scattering or unresolved nonisotropic contributions can reduce its polarization.

Spherical-particle frequency scaling. For a dielectric sphere of radius $a\ll \lambda$, the quasistatic electric polarizability isThe electric dipole radiation formula and $I_0={ϵ}_{0}c|E_0{|}^2/2$ giveThus Rayleigh scattering scales as ${\omega }^4$, or ${\lambda }^{-4}$, when the polarizability varies slowly with frequency. Material resonances and absorption can change this simple scaling. For the incident $z$ polarization, the dipole is along $z$: intensity is proportional to ${\sin }^2\chi$, where $\chi$ is the angle from $z$. There is no radiation on the dipole axis and a maximum in the $xy$ plane. In a direction $\hat{\mathbf{n}}$ the scattered electric field is along $\hat{\mathbf{z}}-(\hat{\mathbf{z}}\cdot \hat{\mathbf{n}})\hat{\mathbf{n}}$, hence linearly polarized wherever nonzero.^[ref]

Needle model used in parts (a)–(d). Let its axis be $\mathbf{u}=(u_x,u_y,u_z)=(\sin \theta \cos \varphi ,\sin \theta \sin \varphi ,\cos \theta )$. A very slender, high-permittivity needle has dominant longitudinal response, so use the rank-one needle polarizability $\mathbf{\alpha }\simeq {\alpha }_{\parallel }\mathbf{u}{\mathbf{u}}^{\mathsf{T}}$. Its transverse response is neglected at leading order. For observation along $y$, define $\mathbf{v}=u_x\hat{\mathbf{x}}+u_z\hat{\mathbf{z}}$, $s=|\mathbf{v}{|}^2=1-u_y^2$ andFor a unit incident Jones vector $\mathbf{e}$, the common far-field relation is ${\mathbf{E}}_s\propto \mathbf{v}(\mathbf{u}\cdot \mathbf{e})$, and $I_s=K{I}_{0}s|\mathbf{u}\cdot \mathbf{e}{|}^2$. Here $I_s$ is irradiance at distance $R$; multiplying by $R^2$ gives power per solid angle. No absolute value of ${\alpha }_{\parallel }$ is given or needed for the requested relative intensities.

Diffuse random cloud, with the incident polarization of (a). The single-particle amplitudes through $x$ and $z$ analysers are proportional to $u_x{u}_z$ and $u_z^2$. The isotropic orientation fourth moment gives the needle-scattering analyzer momentsFor example, $⟨u_z^4⟩=\frac{1}{2}{\int }_{-1}^1{\mu }^{4}d\mu =1/5$; symmetry and $u_x^2+u_y^2+u_z^2=1$ give $2⟨u_x^2{u}_z^2⟩=1/3-1/5$. Since the particles scatter mutually incoherently, intensities add. For $N$ illuminated particles,The cross correlation vanishes by reflection symmetry. The degree of linear polarization is $(I_z-I_x)/(I_z+I_x)=\boxed{1/2}$: random anisotropic scatterers produce partially depolarized light, even though every individual needle produces a single linear polarization.

Continuous homogeneous dielectric. One must sum amplitudes coherently and include their spatial phases, rather than retain the preceding sum of intensities. Random orientations give $⟨\mathbf{u}{\mathbf{u}}^{\mathsf{T}}⟩=\mathbf{I}/3$, so the averaged response is isotropic and its induced polarization is along $z$. Its coherent radiation toward $y$, when allowed by the sample geometry, is therefore purely $z$ polarized, with $I_x=0$. The independent-needle prefactor is no longer a quantitative dense-medium model; local-field and collective effects determine the effective permittivity.

There is also coherent continuum phase matching: a uniform bulk driven by a plane wave has no arbitrary outgoing $90^{\circ }$ plane-wave component. In an ideal infinite homogeneous medium there is no diffuse side scattering at all; propagation, refraction and reflection are determined by the medium and its interfaces. A finite sample's coherent side signal depends on its shape and boundaries. Thus the old $1:3$ diffuse ratio is replaced by a coherent isotropic-medium response, not by a universal nonzero $N^2$ side-scattering intensity.