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Weak transitions in dilute gas. A forbidden emission line is a transition absent in the electric-dipole approximation because of its selection rules, but permitted through weaker channels such as magnetic-dipole or electric-quadrupole radiation, sometimes aided by state mixing. It is not an impossible transition. Its upper atomic level is relatively long lived, so collisions can deactivate it before a photon is emitted in dense gas. Low-density astrophysical plasmas allow radiative decay to compete successfully.

In a schematic two-level statistical equilibrium,The critical density is $n_{\mathrm{crit}}=A_{ul}/q_{ul}$ for this simple level system; multiple radiative and collisional channels require summed rates. At $n_e\ll n_{\mathrm{crit}}$ each collisional excitation is likely to produce radiation, so ${ϵ}_{ul}\propto n_l{n}_e{q}_{lu}h\nu$. At high density collisional de-excitation suppresses the line relative to this low-density expectation. The rate need not decrease absolutely with increasing density; the suppression is relative to the naive excitation scaling.

A temperature-sensitive ratio. For a Maxwell-Boltzmann electron distribution,where ${\rm Y}$ is an effective collision strength. Lines from upper levels with different excitation energies therefore have a strongly temperature-dependent ratio. Using one ion reduces sensitivity to abundance and ionization fraction compared with comparing unrelated species.

A standard example is doubly ionized oxygen: the $4959$ and $5007$ angstrom lines descend from ${}^1{D}_2$ toward the ${}^{3}P$ ground term, while the $4363$ angstrom line connects ${}^1{S}_0$ to ${}^1{D}_2$. The higher excitation threshold makes the auroral $4363$ line relatively stronger in hotter gas. In the low-density Maxwellian approximation, with slowly varying collision strengths,The numerical form is a useful approximation, not a universal exact atomic law; a multilevel atomic calculation with current collision strengths is needed for precise work.^[ref]

In an active galactic nucleus these lines commonly diagnose the relatively dilute narrow-line gas; dense broad-line gas can collisionally quench them. Measure and deblend the fluxes, subtract continuum and stellar features, correct differential extinction, and check density independently. The $5007/4959$ ratio mainly tests radiative branching and calibration because both lines share one upper level; it is not the required temperature thermometer. Temperature gradients, multiple density components, shocks, ionization structure and departures from the Maxwellian electron distribution can bias a single inferred temperature. Without a measured ratio and density regime, no particular AGN temperature is numerically determined here.