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NIST Technical Note1394, January1998. Printed title page names Rodney W. Leonhardt. Section6.2, Laser stability, printedp.23: internal excimer-laser pulse monitor, pyroelectric energy meter, integrated calorimetric energy and averaging over pulses. The report distinguishes pulse variability from its contribution to a calibration result.

Pulse energy measurement with a photodiode estimates incident laser pulse energy from collected signal electric charge. At fixed wavelength, suppose a photodiode has constant calibrated spectral responsivity $R$ in amperes per watt and remains in its linear operating range. If $P(t)$ is the incident radiant flux, the signal photocurrent is $i_{\mathrm{sig}}(t)=RP(t)$. Integrating over the complete response givesThe units agree because amperes per watt equal coulombs per joule. Spectral responsivity must apply at the measurement wavelength; a broadband pulse requires accounting for its spectrum.

In an original example, let $R=0.40\mathrm{A}{\mathrm{W}}^{-1}$ and let the baseline-corrected collected charge be $Q_{\mathrm{sig}}=12\mathrm{nC}$. Then $U=30\mathrm{nJ}$. An ideal charge amplifier with feedback capacitance $C_f=100\mathrm{nF}$ would produce an output change of magnitude $Q_{\mathrm{sig}}/C_f=0.12\mathrm{V}$. The amplifier's polarity depends on its circuit convention.

A practical apparatus needs a calibrated detector, a charge-sensitive readout and a measurement window containing the full response. Detector baseline subtraction removes the estimated background, including dark current. A residual constant current of1microampere integrated over10microseconds contributes10picocoulombs; with the example responsivity this is a25picojoule energy error. Extending the window can capture a missing signal tail but also accumulate more background error.

Photodiode saturation invalidates the assumed constant response. Robert E. Vest and collaborators measured pulsed silicon-detector behavior and reported dependencies on applied reverse bias and illuminated area.^[ref] A low average optical power therefore does not by itself establish linear response to individual pulses.

Rodney W. Leonhardt's calibration report describes a complementary reference method: a slow thermal standard measures accumulated energy, while pulse count and a calibrated beam splitter ratio determine average energy in the test beam.^[ref] This connects a fast photodiode readout to an energy reference without requiring the thermal standard to resolve every pulse.

Collected charge measures energy under the stated assumptions; it does not alone determine peak power. A flat30nanojoule pulse lasting100nanoseconds has power0.30watts, whereas a flat pulse of the same energy lasting1microsecond has power0.030watts. Those stipulated rectangular profiles illustrate why pulse shape and pulse duration are additional information.