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The interior consists exactly of strictly copositive matrices. If $x^{T}Ax$ has positive minimum $\delta$ on the compact nonnegative unit sphere, perturbations of operator norm less than $\delta$ preserve this positive lower bound there. Conversely, if a unit nonnegative vector has zero quadratic form, $A-\epsilon I$ leaves the copositive cone for every $\epsilon >0$. Thus such a matrix is not interior. The identity matrix is a convenient interior point.

A pointed cone has no nonzero line through the origin: equivalently $K\cap (-K)=\{0\}$. If $A\in K\cap (-K)$, its quadratic form vanishes on the nonnegative orthant. Testing the coordinate vectors gives $A_{ii}=0$. Testing $e_i+e_j$ then givesSince $A$ is a symmetric matrix, every entry is zero. Thus $\boxed{K\cap (-K)=\{0\}}$.

The identity matrix gives an interior point. For a symmetric perturbation $E$ with operator norm $\Vert E{\Vert }_2<1$, the Cauchy-Schwarz inequality givesThis open norm ball around $I$ lies even in the positive semidefinite cone, hence in $K$. Consequently $\boxed{I\in \mathrm{int}K}$ and the interior is nonempty.

More generally, the interior of the copositive cone consists exactly of strictly copositive matrices. Positivity on the compact nonnegative unit sphere has a positive minimum and persists under small perturbations; a zero there is destroyed by an arbitrarily small negative multiple of $I$.