Thermal bremsstrahlung is free-free electromagnetic radiation from the acceleration of charged particles during Coulomb encounters in a thermal plasma. Its frequency-integrated emissivity in a fully ionized, nonrelativistic plasma scales approximately as .
For a uniform ionized hydrogen column with known temperature and fixed projected angular area, free-free brightness and optical depth depend on . The displayed rescaling leaves the whole ideal spectrum unchanged. density and path length cannot be separated without additional information. A known geometry/distance, or a distinct column diagnostic proportional to , can break the degeneracy; gas clumping factor and temperature structure complicate that inference.
The fraction of a geometric volume occupied by a specified emitting gas phase is its volume filling factor. For approximately uniform density within that phase, a density-squared luminosity scales as . Without knowledge of , emission gives an rms-density combination rather than a unique mean gas density. This filling factor is distinct from the fraction of a telescope beam occupied on the sky.
For a hydrogen-dominated fully ionized plasma, the line-of-sight emission measure is . Its units distinguish it from a volume-integrated emission measure . Thermal free-free optical depth is proportional to in the radio limit. Inferring density also requires depth, ionization and clumping assumptions.[ref]
The emission coefficient per volume, frequency and solid angle of a Maxwellian plasma has . Define the angular convention before supplying a numerical coefficient. The high-frequency cutoff measures temperature, while the normalization measures a density-squared emission integral. The radio spectrum is almost flat when optically thin and rises as when optically thick at fixed projected area.
For fully ionized hydrogen and helium with hydrogen mass fraction , and . With the same unit Gaunt factor for both species, thermal bremsstrahlung at fixed electron number density is multiplied by relative to pure ionized hydrogen. The factor is one for pure hydrogen and two for pure helium.
The Gaunt factor is the dimensionless quantum correction to a classical free-free radiation calculation. Its weak temperature and frequency dependence modifies the approximate thermal bremsstrahlung scaling; a frequency-averaged value appears in the bolometric cooling coefficient.

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