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Use signature $(+,-,-,-)$ and electron charge $q=-e$, with $e>0$. Then ${\mathcal{L}}_{\mathrm{int}}=-q\bar{\psi }{\gamma }^{\mu }\psi A_{\mu }=+e\bar{\psi }{\gamma }^{\mu }\psi A_{\mu }$. Write the process as $e^{-}(p,s)+\gamma (k,ϵ)\to e^{-}(p^{\prime },s^{\prime })+\gamma (k^{\prime },{ϵ}^{\prime })$. Physical external states satisfyand the photon polarization vectors obey $k\cdot ϵ=k^{\prime }\cdot {ϵ}^{\prime }=0$. Choose unit physical polarizations with ${ϵ}^{\ast }\cdot ϵ={ϵ}^{\prime \ast }\cdot {ϵ}^{\prime }=-1$; representatives differing by a multiple of the corresponding null momentum describe the same physical polarization. The external spinors obey $(/p-m)u(p)=0$, $\bar{u}(p^{\prime })(/p^{\prime }-m)=0$, with ${\bar{u}}_s{u}_r=2m{\delta }_{sr}$. Outgoing polarization appears complex conjugated, so this formula includes helicity states as well as real linear polarizations.

The needed QED Feynman rules are a vertex $-iq{\gamma }^{\mu }=+ie{\gamma }^{\mu }$, an internal Dirac propagator $i(/q+m)/(q^2-m^2+i0)$, the external spinors, and the incoming/outgoing photon polarization vectors. There is no internal photon at this order and no elementary two-photon–Dirac seagull vertex. The two photon orderings along the electron line give internal momenta $q_s=p+k$ and $q_u=p-k^{\prime }$. Defining the matrix element by $S_{fi}-{\delta }_{fi}=i(2\pi {)}^4{\delta }^4(p+k-p^{\prime }-k^{\prime })\mathcal{M}$, their sum isThe denominators are $2p\cdot k+i0$ and $-2p\cdot k^{\prime }+i0$. Both terms are essential; this is the tree-level Compton amplitude.

To prove the incoming Ward identity, replace $ϵ$ by $k$ and write $R(q)=(/q+m)/(q^2-m^2)$, with the Feynman boundary prescription understood. The physical nonzero-photon kinematics keeps these tree denominators off the electron pole. Sincethe external Dirac equations implyTherefore the two contracted terms are $\bar{u}(p^{\prime })/{ϵ}^{\prime \ast }u(p)$ and its negative, and cancel. By linearity,This is the two-photon fermion Ward identity. An analogous cancellation holds for the outgoing photon. Gauge-equivalent polarization representatives have the same scattering amplitude, so a longitudinal pure-gauge component is not an extra physical photon state. Individual diagrams do not generally satisfy this identity; their sum does.

For perturbative order, each elementary QED vertex has one photon leg. If $I_{\gamma }$ is the number of internal photon lines and $E_{\gamma }=2$, the vertex parity of a QED amplitude givesThus there is no third-order contribution. At fourth order, $V=4$ and, counting all three legs per vertex with four external legs, $I=(3V-4)/2=4$. A connected graph has loop number $I-V+1=1$.

The nonzero one-loop classes on the open electron line are an internal-electron self-energy insertion, a vertex correction at either external-photon vertex, and a virtual photon spanning both photon vertices, giving the four-point box class. The first figure sketches each class for one photon ordering; interchange the two external photon attachments for its crossed partner. This yields two internal-self-energy graphs, four vertex graphs and two spanning-box graphs. They use the usual photon propagator, for example $-i{g}_{\mu \nu }/({\ell }^2+i0)$ in Feynman gauge.

For completeness, one-loop diagram classes for Compton scattering also depend on whether one is drawing an unamputated correlation function or a physical amplitude. Electron self-energies can be attached to either external electron leg, and photon vacuum polarization can be attached to either external photon leg, for both photon orders. In an on-shell renormalized S-matrix, these are accounted for by LSZ reduction and external-field residues rather than counted again as independent amputated graphs. Photon-leg corrections are not vacuum-polarization insertions on an internal Born photon: there is no such Born line.

At the same fourth order, a renormalized calculation has one mass or electron-field counterterm on the internal electron line, or one vertex counterterm at either Born vertex; the crossed partners are included. Each counterterm is a relative order-$e^2$ correction to the order-$e^2$ tree amplitude. External-field normalization must follow the same convention.

A possible closed electron loop with three photon vertices, linked to the external electron line by a virtual photon, cancels between its two orientations by Furry's theorem. Transposing the loop and using $C^{-1}{\gamma }^{\mu }C=-({\gamma }^{\mu }{)}^T$ gives an extra sign $(-1{)}^3$, so its orientation-reversed partner is its negative. A one-photon tadpole likewise vanishes. Disconnected vacuum bubbles are removed by vacuum normalization. The first genuine radiative corrections are fourth order, with the internal self-energy, vertex and spanning-box classes and their consistently included renormalization terms.

Take the muon mass to be $m_{\mu }$, and use the quantum electrodynamics convention ${\mathcal{L}}_{\mathrm{int}}=-e\bar{\psi }{\gamma }^{\mu }\psi A_{\mu }$ with $e>0$. Let $p_1,p_2$ be the incoming muon and antimuon momenta and $k_1,k_2$ the outgoing photon momenta, so $p_1+p_2=k_1+k_2$. External particles are on shell: $p_1^2=p_2^2=m_{\mu }^2$ and $k_1^2=k_2^2=0$. The two tree-level Feynman diagrams are the two orders in which the photon legs attach to the muon line. There is no three-photon QED vertex, and therefore no single-photon annihilation diagram into two photons at this order.

The QED Feynman rules needed here are the vertex $-ie{\gamma }^{\mu }$, the Dirac propagatoran incoming muon spinor $u(p_1)$, an incoming antimuon adjoint $\bar{v}(p_2)$, and an outgoing photon polarization ${ϵ}_{\mu }^{\ast }(k)$. At a vertex enforce four-momentum conservation. Spinor products are ordered along the fermion line; exchanging the external photons introduces no relative minus sign. Define $R(q)=(/q+m_{\mu })/(q^2-m_{\mu }^2+i0)$ and $/ϵ={\gamma }^{\mu }{ϵ}_{\mu }$.

With the convention that a diagram contributes $i\mathcal{M}$, the two muon-antimuon annihilation amplitudes areTheir denominators are respectively $t-m_{\mu }^2+i0$ and $u-m_{\mu }^2+i0$, where $t=(p_1-k_1{)}^2$, $u=(p_1-k_2{)}^2$. A different consistent overall amplitude-phase convention has no physical effect.

A physical photon polarization vector obeys $k\cdot ϵ=0$, and represents an equivalence class $ϵ\sim ϵ+\alpha k$. For a real null momentum, adding $\alpha k$ preserves transversality. One can additionally choose transverse spatial vectors with ${ϵ}^0=0$ and ${ϵ}^{\ast }\cdot ϵ=-1$; there are two independent physical polarizations. The equivalence class removes the unphysical longitudinal direction, rather than imposing four independent physical polarization states.

The invariance of the total amplitude is a two-photon fermion Ward identity. Replace ${ϵ}_1^{\ast }$ by $k_1$ and put $q_t=p_1-k_1$, $q_u=p_1-k_2=k_1-p_2$. The external Dirac equations giveAway from propagator poles, $R(q)(/q-m_{\mu })=(/q-m_{\mu })R(q)=I$; the identity extends with the common Feynman prescription. ThereforeThe two terms in the bracket then give $-\bar{v}/{ϵ}_2^{\ast }u$ and $+\bar{v}/{ϵ}_2^{\ast }u$, which cancel. Exchanging photon labels proves the second Ward identity. Thus the sum is unchanged under ${ϵ}_i\mapsto {ϵ}_i+\alpha k_i$ for either photon. Neither diagram is generally gauge-invariant separately. Physically, longitudinal pure-gauge polarization does not couple to the observable scattering amplitude; only the two transverse photon degrees of freedom contribute.

For Compton scattering write the incoming momenta as $p,k$ and outgoing momenta as $p^{\prime },k^{\prime }$, with $p+k=p^{\prime }+k^{\prime }$. The outgoing muon contributes $\bar{u}(p^{\prime })$, the incoming photon contributes $ϵ(k)$ without conjugation, and the outgoing photon contributes ${ϵ}^{\prime \ast }(k^{\prime })$. The two tree-level Compton amplitudes areThese are the lower two diagrams. Their intermediate muon momenta are $p+k$ and $p-k^{\prime }$, with denominators $s-m_{\mu }^2+i0$ and $u-m_{\mu }^2+i0$. The first attaches the incoming photon before the outgoing photon along fermion flow; the second reverses that attachment order. Both contribute at order $e^2$ in the amplitude.

Compton scattering has one incoming and one outgoing muon and one photon on each side; annihilation has an incoming particle-antiparticle pair and two outgoing photons. Accordingly the external spinors/polarizations and physical Mandelstam channels differ, although both arise from the same two-vertex QED matrix element. Crossing symmetry relates them by continuing $p_2\mapsto -p^{\prime }$ and one outgoing photon momentum $k_1\mapsto -k$, with the corresponding external wavefunction replacements. The annihilation $t$ channel becomes the Compton $s$ channel and the other channel becomes its $u$ channel. Identical final photons require a factor $1/2!$ in an annihilation phase-space integral over an otherwise double-counted full final-state region; there is no analogous final-state identical-particle factor for the muon-photon Compton final state. Gauge cancellation holds for the summed Compton amplitude as well.