A tricritical point is the meeting of a line of continuous phase transitions and a line of first-order phase transitions. In the symmetric scalar Landau free energy, it occurs at with . Two independent controls are needed to tune both coefficients. The continuous transition lies at , and the tricritical three-phase line found above has ; both approach the tricritical point. At zero conjugate field the three coexisting states on this first-order line are the disordered state and the two opposite ordered states.
Setting makes the leading stabilizing interaction sextic. The nonzero minimum obeys , so the order-parameter critical exponent along this tuned direction is . Substitution gives
and two temperature derivatives give the heat-capacity critical exponent . At , the equation of state is , giving the critical-isotherm exponent .
For magnetic susceptibility, differentiating gives . This is above the transition and below, hence . The quadratic fluctuation kernel still has a mass proportional to , giving and . Thus the mean-field tricritical exponent calculation yields
Detuning gives tricritical crossover scaling; one must specify the approach to the tricritical point when quoting these critical exponents. The sextic interaction has upper critical dimension three, so sufficiently strong long-distance fluctuations change these mean-field predictions below three dimensions.
A tricritical point requires two independent even coefficients in the Landau free energy to vanish: , with providing stability. At , the ordinary critical line meets the tricritical three-phase line . The order parameter discontinuity along the first-order line is , which goes to zero at their meeting.
The positive sextic coefficient makes this a different leading local potential from an ordinary quartic critical point. Consequently its mean-field critical exponents, crossover behavior and upper critical dimension differ. There are two relevant even tuning directions near the tricritical point, in addition to the conjugate odd field. The root solution and labelled phase diagram display the three controls and the tricritical wings; varying can give a first-order reversal within the ordered coexistence sheet, a first-order weak/strong transition on a wing, or a continuous transition at a wing's ordinary critical edge.
A phase diagram partitions a space of thermodynamic controls into regions with distinct equilibrium phases. Its boundaries indicate phase coexistence or continuous phase transitions; a critical point is a termination of coexistence where the distinction between phases disappears. A concrete three-dimensional control space is for the Blume–Capel model: a spin can be or , the exchange favors aligned nonzero spins, and controls the energetic cost of nonzero spins. Varying changes the balance between a continuous ordering transition and a first-order phase transition. Their meeting is a tricritical point.
Locally, the same structure is displayed by the Landau free energy
with three controls . For , the line consists of ordinary critical points. For , equal free energies of and a nonzero stationary point require
Eliminating gives the tricritical three-phase line
Here and both signs of coexist, with a discontinuous order parameter. Below this line, or below when , the plane is an ordered phase coexistence sheet: crossing it reverses the sign of . Two tricritical wings also extend to nonzero , separating weakly and strongly magnetized states of the same sign. Their ordinary critical points satisfy . Since , their tricritical wing critical edges are
At these edges , giving an ordinary quartic critical expansion around . All these structures end at the tricritical point . The diagrams show both the zero-field section and the genuinely three-dimensional coexistence structure.
Figure 1.
Scalar Landau phase diagram: zero-field transitions, tricritical wings and ordinary critical edges
. Details.
For the final critical exponent calculation, take with , , and hold the other controls fixed. At an ordinary critical point, the quartic term dominates the sextic term. For and ,
whereas on the disordered side the singular contribution is zero. Two temperature derivatives give a finite jump in heat capacity, so . At , the equation of state is , so .
Along the tricritical trajectory , the nonzero minimum obeys and
Thus two temperature derivatives produce . At , . Therefore the mean-field critical exponents are
With the thermodynamic free energy, the physical sign is , rather than the positive sign printed in the paper. This correction affects the sign of the heat capacity, not its critical exponent. The tricritical result assumes that the independent quartic control is tuned to zero; a generic trajectory through nearby ordinary critical points need not have these exponents.
A phase diagram partitions a space of control parameters into regions with distinct equilibrium phases. Its boundaries mark nonanalyticities of the thermodynamic-limit free energy; a first-order phase transition has a jump in a first derivative, whereas a continuous phase transition has a continuously vanishing order parameter and singular fluctuations.
An explicit three-parameter example is the scalar Landau free energy
with parameter axes . These can be realized locally by the temperature, single-ion anisotropy and magnetic field of the Blume–Capel model. The three dimensions here refer to control-parameter space, not necessarily to three spatial dimensions. At , minimizing this potential gives a continuous phase transition at for . For , coexistence occurs at , where
There are three global minima, and . Their order parameter jump decreases to zero as . Thus is a tricritical point. The two transition curves in the plane meet there.
In the three-dimensional phase diagram, crossing inside the ordered region switches between opposite signs of , so that region is itself a first-order phase transition sheet. For , two tricritical wings at opposite nonzero fields separate weakly and strongly magnetized phases. Their wing critical edges can be obtained rather than merely sketched: require . Since , the nonzero solutions satisfy
The fourth derivative there is , giving ordinary continuous critical endpoints. The wings meet the zero-field coexistence sheet along the tricritical three-phase line and terminate at these edges. Their exact tricritical wing coexistence factorization supplies the surfaces in the figure: for two nonnegative minima , set , and
Direct expansion gives , proving that these surfaces describe coexistence of global, not merely local, minima.
Figure 1.
Tricritical phase diagram of the sextic scalar free energy: first-order sheets, critical edges and the zero-field slice
. Details.
For the unheaded Ising model calculation, assume ferromagnetic exchange and let denote the mean Ising spin. On the hypercubic lattice the coordination number of a lattice is , even though the original positive-direction bond sum counts each bond only once. The mean-field approximation neglects products of deviations from :
There are bonds, so the approximate energy is . Each independent Ising spin therefore sees the effective field . With , averaging its two Boltzmann weights gives the self-consistency equation
The slope of its right side at zero is , where
Above , for excludes a nonzero solution. Below the initial slope exceeds one, and concavity of the hyperbolic tangent on the positive axis gives one positive solution and its negative partner. The Ising auxiliary mean-field free energy has positive quartic coefficient near , while its quadratic coefficient changes sign there. Its stable minima therefore move continuously away from zero; this is a continuous phase transition in the mean-field theory of the Ising model.
Put and . The Taylor expansion gives, on the nonzero branch,
Consequently and the mean-field order-parameter exponent is . The inverse-temperature symbol used above is distinct from this order-parameter critical exponent.
Consider the plane at for , with fixed . For , the continuous boundary is : above it the global minimum is zero, and below it there are two symmetry-related ordered pure thermodynamic phases. For , the equilibrium boundary is the tricritical three-phase line
Above this curve the disordered minimum wins; below it the two ordered minima win. On the curve,
Its three zeros are exactly and , proving equality of three global minimum values. Spin inversion symmetry enforces the equality of the two ordered phases automatically, so tuning a single remaining coefficient can produce three-phase coexistence on a line in this symmetry plane. This does not contradict the generic phase-rule counting without symmetry restrictions.
The tricritical point is , where the discontinuity vanishes, the first-order boundary meets the continuous boundary, and the positive sextic term becomes the leading stabilizer. The local metastability limits and , , bracket the first-order curve but are not phase boundaries. In the full parameter space, the zero-field line is attached to tricritical wings; a nonzero field splits the equality of the two ordered phases.
Figure 1.
Zero-field sextic Landau phase diagram, showing the continuous boundary and three-phase coexistence line
. Details.
A tricritical point joins continuous and first-order transition loci and requires tuning an additional temperature-independent control. In the scalar sextic potential
it occurs at : both the quadratic and quartic terms vanish. At , the transition is continuous at ; at , it is first-order at . The jump tends to zero as , so these loci meet at the tricritical point.
For the three-control phase diagram with coordinates , the sheet below these transition loci has coexistence of the two ordered phases. For its boundary is the ordinary continuous critical line . For the boundary is a tricritical three-phase line, where and all coexist. Two symmetry-related tricritical wings extend from that line into and , describing first-order coexistence between small- and large-magnitude phases of the same sign. Each wing ends along an ordinary wing critical edge.
The critical-edge conditions give
Here , so these are ordinary quartic endpoints. The two wing critical edges and the zero-field ordinary critical line are three continuous critical lines meeting at the tricritical point; the three-phase first-order line also ends there. The “3D” phase diagram refers to three independent controls; it is distinct from the spatial dimension of the field theory.
The figure uses actual sextic-potential coexistence surfaces rather than drawing arbitrary wings. For two coexisting nonnegative minima , put . The tricritical wing coexistence factorization
holds when , and . It proves that both minima are globally stable. The limits and produce the three-phase line and critical edge, respectively; reflection gives the other wing.
Figure 1.
Scalar tricritical coexistence wings and the zero-field phase diagram
. Details.
At , on the ordered side and . At the critical isotherm . Thus the tricritical mean-field critical exponents are
The source's extra control is required to tune to zero; simply changing temperature in a generic quartic system does not produce tricriticality. The tricritical upper critical dimension is three, as established in Question 3.