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If phase-randomizing collisions form a Poisson process of mean interval ${\tau }_c$, field correlation survives only when no such collision occurs during the delay. Thus its magnitude decays as $e^{-|\tau |/{\tau }_c}$. The Wiener-Khinchin theorem gives the normalized Lorentzian line shapeIts full width at half maximum is $2/{\tau }_c$ in angular frequency or $1/(\pi {\tau }_c)$ in ordinary frequency. A population lifetime is a different time constant: lifetime-limited amplitude decay at half the population rate introduces the familiar factor of two. The definition of the supplied lifetime must therefore accompany any numerical linewidth.

A non-polarizing beam splitter divides the incident spectrum into a fixed arm and an arm with a translating mirror. Recombining their returned fields gives a detector signal as a function of mirror position $x$. The round-trip optical path difference is $D=2x$ relative to the equal-arm position, so the delay is $\tau =2x/c$ in air approximated as vacuum. Record both detector signal and calibrated position, subtract the constant background, and take a Fourier transform of the interferogram.

For matched arm polarizations and balanced throughput, write the ideal signal aswhere $S(\omega )$ is the incident spectral power density and $C$ is a constant set by the beam splitter and detector. This is the cosine-transform form of Fourier transform spectroscopy, or equivalently the Wiener-Khinchin theorem applied to delayed self-interference.

The delay-range resolution in Fourier transform spectroscopy follows because recording a finite delay range multiplies the correlation by a window. Its transform broadens each spectral line by an instrumental width of order the reciprocal delay range. A mirror travel range $L$ creates a delay range of order $2L/c$, soAt fixed wavelength, absolute wavelength resolution therefore improves inversely with travel range. The numerical coefficient depends on whether $L$ is a one-sided or total travel, on the window or apodization, and on whether resolution means first zero, half width or another criterion. The proportionality is the requested convention-independent result. Position sampling must also be fine enough to sample the fastest fringe variation without aliasing.

A line with lifetime broadening has a Lorentzian line shape. Write its half-width at half-maximum in angular-frequency units as $\kappa >0$. The Wiener-Khinchin theorem, or the Fourier transform of the Lorentzian, givesTherefore in vacuumThe sketch is a cosine fringe pattern about baseline $I_0$, bounded by $I_0[1\pm e^{-\sqrt{2}\kappa |y|/c}]$. Its central value is $2I_0$, its spatial interference fringe spacing is $\lambda /\sqrt{2}$, and its visibility decays on length $c/(\sqrt{2}\kappa )$. For an isolated transition whose population lifetime is $T_1$ and which has no extra dephasing, $\kappa =1/(2T_1)$, so the field coherence time is $2T_1$, not $T_1$. Introducing $\kappa$ avoids confusing population, wave amplitude and spectral-width conventions when no numerical linewidth is given.

The Wiener-Khinchin theorem relates the autocorrelation of a weakly stationary process to its power spectral density by a Fourier transform. The displayed convention is appropriate when the optical correlation is $\Gamma (\tau )=⟨f^{\ast }(t)f(t+\tau )⟩$ and the analytic field contains $e^{-i\omega t}$. A Lorentzian line shape of half-width $\kappa$ gives exponential correlation decay $e^{-\kappa |\tau |}$, including the carrier factor $e^{-i\omega \tau }$ when the full field is correlated.