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Why can't you collimate incoherent light as well as a laser? Updated +Created
You could put an LED in a cavity with a thin long hole but then, most rays, which are not aligned with the hole, will just bounce inside forever producing heat.
So you would have a very hot device, and very little efficiency on the light output. This heat might also behave like a black-body radiation source, so you would not have a single frequency.
The beauty of lasers is the laser cavity (two parallel mirrors around the medium) selects parallel motion preferentially, see e.g.: youtu.be/_JOchLyNO_w?t=832 from Video "How Lasers Work by Scientized (2017)"
Why do multiple electrons occupy the same orbital if electrons repel each other? Updated +Created
That is, two electrons per atomic orbital, each with a different spin.
As shown at Schrödinger equation solution for the helium atom, they do repel each other, and that affects their measurable energy.
However, this energy is still lower than going up to the next orbital. TODO numbers.
This changes however at higher orbitals, notably as approximately described by the aufbau principle.
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