Incoming links: Classical mechanics
Basically the same as classical mechanics.
Theory that gases are made up of a bunch of small billiard balls that don't interact with each other.
This theory attempts to deduce/explain properties of matter such as the equation of state in terms of classical mechanics.
Published by Werner Heisenberg in 1925-07-25 as quantum mechanical re-interpretation of kinematic and mechanical relations by Heisenberg (1925), it offered the first general formulation of quantum mechanics.
It is apparently more closely related to the ladder operator method, which is a more algebraic than the more analytical Schrödinger equation.
It appears that this formulation makes the importance of the Poisson bracket clear, and explains why physicists are so obsessed with talking about position and momentum space. This point of view also apparently makes it clearer that quantum mechanics can be seen as a generalization of classical mechanics through the Hamiltonian.
QED and the men who made it: Dyson, Feynman, Schwinger, and Tomonaga by Silvan Schweber (1994) mentions however that relativistic quantum mechanics broke that analogy, because some 2x2 matrix had a different form, TODO find that again.
Inward Bound by Abraham Pais (1988) chapter 12 "Quantum mechanics, an essay" part (c) "A chronology" has some ultra brief, but worthwhile mentions of matrix mechanics and the commutator.
This section is more precisely about classical mechanics.
Experiments explained:
- via the Schrödinger equation solution for the hydrogen atom it predicts:
- spectral line basic lines, plus Zeeman effect
- Schrödinger equation solution for the helium atom: perturbative solutions give good approximations to the energy levels
- double-slit experiment: I think we have a closed solution for the max and min probabilities on the measurement wall, and they match experiments
Experiments not explained: those that the Dirac equation explains like:
The easiest to understand case of the equation which you must have in mind initially that of the Schrödinger equation for a free one dimensional particle.
Then, with that in mind, the general form of the Schrödinger equation is:where:
Equation 1.
Schrodinger equation
. - is the reduced Planck constant
- is the wave function
- is the time
- is a linear operator called the Hamiltonian. It takes as input a function , and returns another function. This plays a role analogous to the Hamiltonian in classical mechanics: determining it determines what the physical system looks like, and how the system evolves in time, because we can just plug it into the equation and solve it. It basically encodes the total energy and forces of the system.
The argument of could be anything, e.g.:Note however that there is always a single magical time variable. This is needed in particular because there is a time partial derivative in the equation, so there must be a corresponding time variable in the function. This makes the equation explicitly non-relativistic.
- we could have preferred polar coordinates instead of linear ones if the potential were symmetric around a point
- we could have more than one particle, e.g. solutions of the Schrodinger equation for two electrons, which would have e.g. and for different particles. No matter how many particles there are, we have just a single , we just add more arguments to it.
- we could have even more generalized coordinates. This is much in the spirit of Hamiltonian mechanics or generalized coordinates
The general Schrödinger equation can be broken up into a trivial time-dependent and a time-independent Schrödinger equation by separation of variables. So in practice, all we need to solve is the slightly simpler time-independent Schrödinger equation, and the full equation comes out as a result.
We select for the general Equation "Schrodinger equation":giving the full explicit partial differential equation:
- , the linear cartesian coordinate in the x direction
- , which analogous to the sum of kinetic and potential energy in classical mechanics
Equation 1.
Schrödinger equation for a one dimensional particle
. The corresponding time-independent Schrödinger equation for this equation is:
Equation 2.
time-independent Schrödinger equation for a one dimensional particle
. A single line in the emission spectrum.
So precise, so discrete, which makes no sense in classical mechanics!
Has been the leading motivation of the development of quantum mechanics, all the way from the:
- Schrödinger equation: major lines predicted, including Zeeman effect, but not finer line splits like fine structure
- Dirac equation: explains fine structure 2p spin split due to electron spin/orbit interactions, but not Lamb shift
- quantum electrodynamics: explains Lamb shift
- hyperfine structure: due to electron/nucleus spin interactions, offers a window into nuclear spin