This is not a truly "fundamental" constant of nature like say the speed of light or the Planck constant.
Rather, it is just a definition of our Kelvin temperature scale, linking average microscopic energy to our macroscopic temperature scale.
The way to think about that link is, at 1 Kelvin, each particle has average energy:per degree of freedom.
For an ideal monatomic gas, say helium, there are 3 degrees of freedom. so each helium atom has average energy:
If we have 2 atoms at 1 K, they will have average energy , and so on.
Another conclusion is that this defines temperature as being proportional to the total energy. E.g. if we had 1 helium atom at 2 K then we would have about energy, 3 K and so on.
This energy is of course just an average: some particles have more, and others less, following the Maxwell-Boltzmann distribution.
Inward Bound by Abraham Pais (1988) page 282 shows how this can be generalized from the Maxwell-Boltzmann distribution
Maxwell-Boltzmann vs Bose-Einstein vs Fermi-Dirac statistics Updated 2024-12-15 +Created 2024-10-28
Maxwell-Boltzmann statistics, Bose-Einstein statistics and Fermi-Dirac statistics all describe how energy is distributed in different physical systems at a given temperature.
For example, Maxwell-Boltzmann statistics describes how the speeds of particles are distributed in an ideal gas.
The temperature of a gas is only a statistical average of the total energy of the gas. But at a given temperature, not all particles have the exact same speed as the average: some are higher and others lower than the average.
For a large number of particles however, the fraction of particles that will have a given speed at a given temperature is highly deterministic, and it is this that the distributions determine.
One of the main interest of learning those statistics is determining the probability, and therefore average speed, at which some event that requires a minimum energy to happen happens. For example, for a chemical reaction to happen, both input molecules need a certain speed to overcome the potential barrier of the reaction. Therefore, if we know how many particles have energy above some threshold, then we can estimate the speed of the reaction at a given temperature.
The three distributions can be summarized as:
- Maxwell-Boltzmann statistics: statistics without considering quantum statistics. It is therefore only an approximation. The other two statistics are the more precise quantum versions of Maxwell-Boltzmann and tend to it at high temperatures or low concentration. Therefore this one works well at high temperatures or low concentrations.
- Bose-Einstein statistics: quantum version of Maxwell-Boltzmann statistics for bosons
- Fermi-Dirac statistics: quantum version of Maxwell-Boltzmann statistics for fermions. Sample system: electrons in a metal, which creates the free electron model. Compared to Maxwell-Boltzmann statistics, this explained many important experimental observations such as the specific heat capacity of metals. A very cool and concrete example can be seen at youtu.be/5V8VCFkAd0A?t=1187 from Video "Using a Photomultiplier to Detect single photons by Huygens Optics" where spontaneous field electron emission would follow Fermi-Dirac statistics. In this case, the electrons with enough energy are undesired and a source of noise in the experiment.
A good conceptual starting point is to like the example that is mentioned at The Harvest of a Century by Siegmund Brandt (2008).
Consider a system with 2 particles and 3 states. Remember that:
- in quantum statistics (Bose-Einstein statistics and Fermi-Dirac statistics), particles are indistinguishable, therefore, we might was well call both of them
A
, as opposed toA
andB
from non-quantum statistics - in Bose-Einstein statistics, two particles may occupy the same state. In Fermi-Dirac statistics
Therefore, all the possible way to put those two particles in three states are for:
- Maxwell-Boltzmann distribution: both A and B can go anywhere:
State 1 State 2 State 3 AB AB AB A B B A A B B A A B B A - Bose-Einstein statistics: because A and B are indistinguishable, there is now only 1 possibility for the states where A and B would be in different states.
State 1 State 2 State 3 AA AA AA A A A A A A - Fermi-Dirac statistics: now states with two particles in the same state are not possible anymore:
State 1 State 2 State 3 A A A A A A
These are neutrons that have reached the thermal equilibrium according to the Maxwell-Boltzmann distribution after having bounced around many times without undergoing neutron capture.
Good fissile material is material that is able to absorb thermal neutrons and continue the reaction, because that's the type of neutron you end up getting the most of.