Ciro Santilli @cirosantilli 34

 Incoming links: Spontaneous emission

Dirac equation  Updated 2024-12-15  +Created 1970-01-01

Adds special relativity to the Schrödinger equation, and the following conclusions come basically as a direct consequence of this!

Experiments explained:

spontaneous emission coefficients.
fine structure, notably for example Dirac equation solution for the hydrogen atom
antimatter
particle creation and annihilation

Experiments not explained: those that quantum electrodynamics explains like:

Lamb shift
TODO: quantization of the electromagnetic field as photons?

The Dirac equation is a set of 4 partial differential equations on 4 complex valued wave functions. The full explicit form in Planck units is shown e.g. in Video 1. "Quantum Mechanics 12a - Dirac Equation I by ViaScience (2015)" at youtu.be/OCuaBmAzqek?t=1010:

i \partial_{t} ⎣ ⎢ ⎢ ⎢ ⎡ ψ_{1} ψ_{2} ψ_{3} ψ_{4} ⎦ ⎥ ⎥ ⎥ ⎤ = - i \partial_{x} ⎣ ⎢ ⎢ ⎢ ⎡ ψ_{4} ψ_{3} ψ_{2} ψ_{1} ⎦ ⎥ ⎥ ⎥ ⎤ + \partial_{y} ⎣ ⎢ ⎢ ⎢ ⎡ - ψ_{4} ψ_{3} - ψ_{2} ψ_{1} ⎦ ⎥ ⎥ ⎥ ⎤ - i \partial_{z} ⎣ ⎢ ⎢ ⎢ ⎡ ψ_{3} - ψ_{4} ψ_{1} - ψ_{2} ⎦ ⎥ ⎥ ⎥ ⎤ + m ⎣ ⎢ ⎢ ⎢ ⎡ ψ_{1} ψ_{2} - ψ_{3} - ψ_{4} ⎦ ⎥ ⎥ ⎥ ⎤

(1)

Equation 1.

Expanded Dirac equation in Planck units

Then as done at physics.stackexchange.com/questions/32422/qm-without-complex-numbers/557600#557600 from why are complex numbers used in the Schrodinger equation?, we could further split those equations up into a system of 8 equations on 8 real-valued functions.

Video 1.

Quantum Mechanics 12a - Dirac Equation I by ViaScience (2015)

Source.

Video 2.

PHYS 485 Lecture 14: The Dirac Equation by Roger Moore (2016)

Source.

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Laser  Updated 2024-12-15  +Created 1970-01-01

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What makes lasers so special: Lasers vs other light sources.

Video 1.

How Lasers Work by Scientized (2017)

Source.

An extremely good overview of how lasers work. Clearly explains the electron/photon exchange processes involved, notably spontaneous emission.

Talks about the importance of the metastable state to achieve population inversion.

Also briefly explains the imperfections that lead to the slightly imperfect non punctual spectrum seen in a real laser.

youtu.be/_JOchLyNO_w?t=188 says LED is "also monochromatic", but that is not strictly true, it has way way larger frequency band than a laser. Only narrower compared to other sources such as incandescent light bulbs.
youtu.be/_JOchLyNO_w?t=517 stimulated emission. This is the key to laser formation as it produces coherent photons.
youtu.be/_JOchLyNO_w?t=581 spontaneous emission happens too fast (100 ns), which is not enough time for stimulated emission to happen. Metastable electrons to the rescue.
youtu.be/_JOchLyNO_w?t=832 the parallel mirrors select perpendicular photons preferentially

Video 2.

Laser Fundamentals I by Shaoul Ezekiel

. Source. 2008, MIT. Many more great videos in this series.

Bibliography:

phys.libretexts.org/Courses/University_of_California_Davis/UCD%3A_Physics_9HE_-_Modern_Physics/06%3A_Emission_and_Absorption_of_Photons/6.3%3A_Lasers His Rate My Professors is amazing: www.ratemyprofessors.com/ShowRatings.jsp?tid=1783467

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Metastable electron  Updated 2024-12-15  +Created 1970-01-01

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A fundamental component of three-level lasers.

As mentioned at youtu.be/_JOchLyNO_w?t=581 from Video "How Lasers Work by Scientized (2017)", they stay in that state for a long time compared to non spontaneous emission of metastable states!

phys.libretexts.org/Courses/University_of_California_Davis/UCD%3A_Physics_9HE_-_Modern_Physics/06%3A_Emission_and_Absorption_of_Photons/6.3%3A_Lasers mentions that they are kept in that excited state due to selection rules.

This is also one of mechanisms behind phosphorescence with triplet states.

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Schrödinger equation  Updated 2024-12-15  +Created 1970-01-01

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The partial differential equation of non-relativistic quantum mechanics.

Experiments explained:

via the Schrödinger equation solution for the hydrogen atom it predicts:
- spectral line basic lines, plus Zeeman effect
Schrödinger equation solution for the helium atom: perturbative solutions give good approximations to the energy levels
double-slit experiment: I think we have a closed solution for the max and min probabilities on the measurement wall, and they match experiments

Experiments not explained: those that the Dirac equation explains like:

fine structure
spontaneous emission coefficients

To get some intuition on the equation on the consequences of the equation, have a look at:

The easiest to understand case of the equation which you must have in mind initially that of the Schrödinger equation for a free one dimensional particle.

Then, with that in mind, the general form of the Schrödinger equation is:

i ℏ \frac{\partial ψ ( x , t )}{\partial t} = \hat{H} [ψ (x, t)]

(1)

Equation 1.

Schrodinger equation

where:

$ℏ$ is the reduced Planck constant
$ψ$ is the wave function
$t$ is the time
$\hat{H}$ is a linear operator called the Hamiltonian. It takes as input a function $ψ$ , and returns another function. This plays a role analogous to the Hamiltonian in classical mechanics: determining it determines what the physical system looks like, and how the system evolves in time, because we can just plug it into the equation and solve it. It basically encodes the total energy and forces of the system.

The

x

argument of

ψ

could be anything, e.g.:

we could have preferred polar coordinates instead of linear ones if the potential were symmetric around a point
we could have more than one particle, e.g. solutions of the Schrodinger equation for two electrons, which would have e.g. $x_{1}$ and $x_{2}$ for different particles. No matter how many particles there are, we have just a single $ψ$ , we just add more arguments to it.
we could have even more generalized coordinates. This is much in the spirit of Hamiltonian mechanics or generalized coordinates

Note however that there is always a single magical

t

time variable. This is needed in particular because there is a time partial derivative in the equation, so there must be a corresponding time variable in the function. This makes the equation explicitly non-relativistic.

The general Schrödinger equation can be broken up into a trivial time-dependent and a time-independent Schrödinger equation by separation of variables. So in practice, all we need to solve is the slightly simpler time-independent Schrödinger equation, and the full equation comes out as a result.

Existence and uniqueness: mathoverflow.net/questions/212913/existence-and-uniqueness-for-two-dimensional-time-dependent-schr%C3%B6dinger-equation

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