Thermodynamic equations are mathematical expressions that describe the relationships between various physical properties of a system in thermodynamics. They are used to analyze how energy, heat, work, and matter interact within a system and with its surroundings. The equations can represent different laws of thermodynamics, state functions, and processes. Here are some key thermodynamic equations and concepts: ### 1. **First Law of Thermodynamics:** This law is a statement of the conservation of energy principle.
The Antoine equation is a mathematical expression used to relate the vapor pressure of a pure substance to its temperature. It provides a way to estimate the vapor pressure of a liquid at various temperatures, which is particularly useful in fields such as chemistry, chemical engineering, and thermodynamics.
Boltzmann's entropy formula is a fundamental equation in statistical mechanics that relates the entropy \( S \) of a system to the number of microstates \( \Omega \) associated with that system. The formula is expressed as: \[ S = k \ln \Omega \] where: - \( S \) is the entropy of the system. - \( k \) is Boltzmann's constant (\( k \approx 1.
Bridgman's thermodynamic equations refer primarily to a set of relations that describe the behavior of certain thermodynamic systems, particularly those involving phase transitions and the effects of pressure and temperature on thermodynamic properties. These equations were developed by the American physicist Percy Williams Bridgman, who made significant contributions to the field of thermodynamics, especially under conditions of high pressure. Bridgman's work often focused on the relationships among pressure, volume, temperature, and entropy in various phases of materials.
The Bromley equation is a mathematical formulation used in the field of geophysics, particularly in studies related to subsurface geology and hydrocarbon reservoirs. It is primarily utilized to estimate the porosity of a rock based on its density and sonic velocity measurements. However, it is essential to note that there might be different contexts for the term "Bromley equation," as it can refer to various equations or models depending on the specific scientific discipline.
Davies' equation, often referred to in the context of crystal plasticity and materials science, provides a relation for the flow stress of materials as a function of temperature. It is often used to describe the behavior of metals under stress, especially at elevated temperatures. In a more specific formulation, Davies' equation can be used to express the temperature dependence of yield strength or flow stress (\(\sigma\)), often including terms for the stress state, strain rate, and other factors.
The Duhem-Margules equation is a thermodynamic relationship that describes the behavior of a binary solution in terms of its components’ chemical potentials and mole fractions. It is particularly important in physical chemistry and chemical engineering for understanding phase equilibria in mixtures.
Ehrenfest equations describe the time evolution of the average values of position and momentum in quantum mechanics, particularly in the context of the interaction between classical and quantum systems. Named after the physicist Paul Ehrenfest, these equations establish a bridge between classical mechanics and quantum mechanics by showing how certain classical quantities can be derived from quantum mechanical expectations. In a typical setting, consider a quantum system described by a Hamiltonian \( H \).
Eötvös rule, named after Hungarian physicist Loránd Eötvös, is an empirical rule in geophysics that describes the relationship between the density of a fluid and the gravitational force acting on it. Specifically, it states that the gravitational attraction of a fluid is proportional to its density when considering the gravitational potential difference over a vertical column of that fluid.
The Gibbs–Duhem equation is a relationship in thermodynamics that describes the changes in the chemical potential of a system in relation to its temperature, pressure, and composition. It arises from the fundamental thermodynamic definition of the differential change in the Gibbs free energy \( G \).
The Gibbs-Helmholtz equation is a thermodynamic relation that connects the Gibbs free energy (G) and the enthalpy (H) of a system to its temperature (T) and entropy (S). It is often expressed in the context of changes in standard conditions and is particularly useful in determining equilibrium constants and reaction spontaneity.
The Gibbs–Thomson equation describes the relationship between the curvature of a phase boundary and the thermodynamic properties of that phase. It is particularly important in the fields of materials science, thermodynamics, and physical chemistry, as it relates to the stability of small particles, droplets, and other interfaces.
The Mason equation, also known as Mason's gain formula, is a fundamental concept in control theory and signal flow analysis, particularly in the context of electrical engineering and systems analysis. It provides a systematic method to determine the transfer function of a linear time-invariant (LTI) system represented as a signal flow graph. In a signal flow graph, systems are represented as nodes (variables) and directed edges (dependencies between variables).
Maxwell's relations are a set of equations in thermodynamics that arise from the equality of mixed second derivatives of thermodynamic potentials. They provide a connection between different thermodynamic properties and facilitate calculations involving changes in state variables. Maxwell's relations are derived from the fundamental thermodynamic potentials: the internal energy \( U \), the Helmholtz free energy \( F \), the Gibbs free energy \( G \), and the enthalpy \( H \).
Mayer's relation is a thermodynamic relationship that connects specific heats of a substance. It is particularly relevant in the study of ideal gases.
The Noro-Frenkel law of corresponding states is a principle in thermodynamics that describes the behavior of fluids (especially gases and liquids) in a system by using reduced variables. It states that the properties of gases and liquids at corresponding states (i.e., states that have the same reduced temperature, reduced pressure, and reduced volume) will be similar, regardless of the substance.
The Ostwald–Freundlich equation is a relationship used in the study of adsorption phenomena, particularly in physical chemistry and materials science. It provides a way to express the dependence of the amount of a substance adsorbed on a solid surface at a given temperature and pressure.
The Pitzer equations, developed by K. S. Pitzer in the 1970s, are used to describe the thermodynamic properties of electrolyte solutions. They provide a way to calculate activity coefficients of ions in solution, which are essential for understanding how ions behave in various concentrations, particularly in solutions with high ionic strength. The Pitzer equations account for interactions between different ions and the resulting deviations from ideal behavior in the solutions.
Stefan's formula relates to the process of phase change, specifically the heat transfer involved in the melting or freezing of a material. It is often used in the context of melting ice or other similar processes where a solid changes into a liquid. The formula is named after the physicist Josef Stefan.
The Szyszkowski equation is a mathematical relationship used in the field of adsorption science. It describes the adsorption of a solute onto an adsorbent material and can be particularly useful in studying the behavior of various substances in terms of their adsorption isotherms.
A table of thermodynamic equations provides a collection of key equations and relationships used in thermodynamics, which is the study of the relationships between heat, work, temperature, and energy. These equations are fundamental for understanding various thermodynamic processes and systems. Below is a summary of some important thermodynamic equations organized by categories: ### 1.
Tetens' equation is a mathematical formula used to estimate the saturation vapor pressure of water based on temperature. It provides a way to calculate the vapor pressure in meteorological and climate studies.
The Van Laar equation is a mathematical expression used in chemical engineering and thermodynamics to describe the activity coefficients of components in a binary mixture. It is particularly useful for assessing the non-ideal behavior of liquid mixtures and is often applied to solutions where the interactions between different types of molecules significantly impact the system's thermodynamic properties.
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