The generalized Leibniz rule follows by mathematical induction. The case is the identity . Suppose the formula holds for and differentiate every term using the product rule:
For an interior index , the coefficient of becomes by Pascal's identity. The two endpoint coefficients are one. This proves
Only finitely many derivatives are involved; it suffices that both functions are times differentiable.
For and , the derivatives of beyond order two vanish. The three surviving terms of the generalized Leibniz rule give
The simplified expression works for every integer , including the two cases where one or more of the three terms are absent.
For and , use . Again only three terms survive. With , they are
Since and , this becomes
The factors and remove the nonexistent terms when or .
If for a twice continuously differentiable potential , then and . Equality of mixed partial derivatives gives the necessary condition for an exact differential:
This condition alone does not ensure global exactness on a domain with holes.
For the Helmholtz free energy , use the stated identity for internal energy and the product rule:
Thus and . Equality of mixed partial derivatives yields the Maxwell relation
The temperature and volume are the independent variables here, with composition and amount of gas fixed.
Next express and substitute its total differential into :
Matching the coefficient of gives
This is the thermodynamic internal pressure identity: an equation of state determines how internal energy changes under an isothermal change of volume.
For the Dieterici equation, set while differentiating at fixed . Then
Substitute into the thermodynamic internal pressure identity. The term proportional to cancels , leaving
The physical gas domain has and .
For the ideal gas instead, gives . Therefore is independent of volume at fixed amount of gas. Integrating the remaining condition , with constant heat capacity at constant volume, gives
where is independent of both and and fixes the reference for internal energy.
For an times continuously differentiable function, Taylor's theorem gives
where lies between and . An infinite Taylor series represents the function when its remainder tends to zero; this holds locally for an analytic function, rather than for every smooth function automatically.
Write and . Away from the origin, and . The product rule gives
Consequently the divergence of is zero. For any closed surface bounding a region that excludes the origin, the field is smooth throughout that region, and the divergence theorem proves
For the infinite cylinder, use and outward unit normal . With , , , and . Hence the direct surface flux is
The integrand is odd in and absolutely integrable. This calculation treats the unbounded cylindrical side directly, without applying the bounded-region divergence theorem across the field's singularity.

Pinned article: Introduction to the OurBigBook Project

Welcome to the OurBigBook Project! Our goal is to create the perfect publishing platform for STEM subjects, and get university-level students to write the best free STEM tutorials ever.
Everyone is welcome to create an account and play with the site: ourbigbook.com/go/register. We belive that students themselves can write amazing tutorials, but teachers are welcome too. You can write about anything you want, it doesn't have to be STEM or even educational. Silly test content is very welcome and you won't be penalized in any way. Just keep it legal!
We have two killer features:
  1. topics: topics group articles by different users with the same title, e.g. here is the topic for the "Fundamental Theorem of Calculus" ourbigbook.com/go/topic/fundamental-theorem-of-calculus
    Articles of different users are sorted by upvote within each article page. This feature is a bit like:
    • a Wikipedia where each user can have their own version of each article
    • a Q&A website like Stack Overflow, where multiple people can give their views on a given topic, and the best ones are sorted by upvote. Except you don't need to wait for someone to ask first, and any topic goes, no matter how narrow or broad
    This feature makes it possible for readers to find better explanations of any topic created by other writers. And it allows writers to create an explanation in a place that readers might actually find it.
    Figure 1.
    Screenshot of the "Derivative" topic page
    . View it live at: ourbigbook.com/go/topic/derivative
  2. local editing: you can store all your personal knowledge base content locally in a plaintext markup format that can be edited locally and published either:
    This way you can be sure that even if OurBigBook.com were to go down one day (which we have no plans to do as it is quite cheap to host!), your content will still be perfectly readable as a static site.
    Figure 5. . You can also edit articles on the Web editor without installing anything locally.
    Video 3.
    Edit locally and publish demo
    . Source. This shows editing OurBigBook Markup and publishing it using the Visual Studio Code extension.
  3. https://raw.githubusercontent.com/ourbigbook/ourbigbook-media/master/feature/x/hilbert-space-arrow.png
  4. Infinitely deep tables of contents:
    Figure 6.
    Dynamic article tree with infinitely deep table of contents
    .
    Descendant pages can also show up as toplevel e.g.: ourbigbook.com/cirosantilli/chordate-subclade
All our software is open source and hosted at: github.com/ourbigbook/ourbigbook
Further documentation can be found at: docs.ourbigbook.com
Feel free to reach our to us for any help or suggestions: docs.ourbigbook.com/#contact