 Most probable speed in the Maxwell distribution

The most probable speed is the mode, or density maximum, of the Maxwell speed distribution:For small equal-width speed bins, the bin near $v_{\mathrm{mp}}$ contains the largest expected fraction of particles. This does not mean that any exact speed has positive probability, or that every particle has this speed. The three common summaries obeyso $v_{\mathrm{mp}}<⟨v⟩<v_{\mathrm{rms}}$. The first describes a density peak, the second the mean speed, and the third the root mean square associated with kinetic energy. ^[ref]

For a concrete scale $s=300\mathrm{m}{\mathrm{s}}^{-1}$, these are approximately $424$, $479$, and $520\mathrm{m}{\mathrm{s}}^{-1}$. The most probable velocity vector and each most probable component remain zero in the gas rest frame. A zero vector labels one small region of velocity space, whereas a positive speed labels an entire spherical shell.

A short check uses the derivative of the logarithm of the Maxwell speed distribution for $v>0$:It is positive below $\sqrt{2}s$ and negative above it, locating the unique peak. The factor $v^2$ from the spherical shell supplies the term $2/v$; omitting it would incorrectly move the speed peak to zero.