 Radiation pressure of an isotropic photon gas

For radiation in vacuum with isotropy, energy is distributed equally per solid angle: write $u_{\Omega }=u/(4\pi )$ for energy density per unit solid angle. Let $\theta$ be the angle between a ray's path and the wall normal. Its normal velocity $c\cos \theta$ determines the arrival rate, while normal momentum per energy is $\cos \theta /c$. Their product is ${\cos }^2\theta$. For a perfectly reflecting cavity wall,The leading two is the normal momentum reversal; the incoming hemisphere contains half of the field's directional energy density. This is also the normal component of the bulk pressure tensor, $P_{nn}={\int }_{4\pi }{u}_{\Omega }{\cos }^2\theta d\Omega =u/3$. Isotropy makes all three diagonal components equal, while their sum is $u$ because the squared direction components sum to one. The factor one third therefore depends on three-dimensional angular geometry, not on the shape of the blackbody radiation spectrum.

A perfectly absorbing wall exposed to this incoming hemisphere receives only $u/6$ from absorption. If it is in thermal equilibrium with the isotropic radiation, its outgoing emission supplies another $u/6$ of recoil, recovering $u/3$. A cold absorber before equilibrium is a different boundary condition. Similarly, the one-way incident energy flux is $cu/4$, whereas the net energy flux across a plane in the undisturbed isotropic field is zero. Dividing $cu/4$ by $c$ misses the extra normal-momentum projection and does not give the cavity pressure.

For a stipulated isotropic radiation energy density $u=6\mu \mathrm{J}{\mathrm{m}}^{-3}$, the bulk pressure is $2\mu \mathrm{Pa}$ regardless of its spectral shape. In thermal equilibrium, blackbody radiation supplies $u=a_{\mathrm{rad}}{T}^4$ with radiation constant $a_{\mathrm{rad}}=4\sigma /c$, so $p_{\mathrm{rad}}=a_{\mathrm{rad}}{T}^4/3$; Stefan–Boltzmann law defines $\sigma$. The equilibrium photon gas derives this same equation of state from its free energy.^[ref]