Chlorine-35 is a stable isotope of chlorine, with 17 protons and 18 neutrons in its atomic nucleus. Its mass number is , while its measured relative atomic mass is approximately . NIST lists representative natural fractions for chlorine-35 and for chlorine-37.[ref]
Atomic Weights and Isotopic Compositions for All Elements by National Institute of Standards and Technology. Chlorine rows 35 and 37, masses and compositions
Those fractions explain a characteristic mass spectrometry pattern. In an idealized sample of with independently paired isotope identities, the three molecular combinations have probabilitiesThe middle term has a factor of two because either atom can be the heavier isotope. For singly charged molecular ions, the combinations give nominal mass peaks at 70, 72 and 74. A mass spectrometer separates ions by mass-to-charge ratio, so the two-unit spacing encodes isotope composition rather than three different chemical elements. These are ideal abundance predictions; actual peak intensities also depend on fragmentation and instrumental response.
Chlorine-35 is the stable daughter in sulfur-35 beta-minus decay: increases from 16 to 17 while the mass number remains 35.[ref] Neither that origin nor the presence of chlorine-35 makes an ordinary chlorine-containing compound radioactive.
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