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Assume zero temperature, the linear Dirac cone, and both real-spin states and both electronic valleys. Define $n$ as excess electron number per unit area, negative for an excess of electron holes, relative to neutrality. A filled circular region of radius $k_F$ in wave vector space containsThus the excess carrier density grows quadratically with the Fermi energy, unlike the constant density of states of a parabolic two-dimensional band. Differentiating gives the positive density of states per unit area, $D(E)=2|E|/[\pi (\hslash v_F{)}^2]$. Both the geometry of occupied states and the fourfold degeneracy matter to the coefficient.

At either displayed wave vector, the three complex hopping amplitudes add to zero: $1+2\cos (2\pi /3)=0$. Therefore the energy bands touch. There are two inequivalent electronic valleys; other equivalent corners are related by reciprocal-lattice translations. Setting $\mathbf{k}={\mathbf{K}}_{\tau }+\mathbf{q}$ and retaining first-order terms giveswhere ${\sigma }_x,{\sigma }_y$ are Pauli matrices. For example, at ${\mathbf{K}}_{+}$, $f\simeq -3b(q_x-i{q}_y)/2$. The matrix has the form of a massless two-dimensional Dirac Hamiltonian. Here $v_F$ is a material-model velocity, rather than the vacuum speed of light; this description does not change an electron's vacuum rest mass. It describes the dispersion relation of electronic excitations near a band crossing.

Let the sample area be $A$, set the band touching energy to zero, and write $m^{\ast }=m_e^{\ast }=m_h^{\ast }$. Assume one electronic valley in each energy band with two spin states. The near-edge parabolic dispersions areUnder periodic boundary conditions, each spin occupies reciprocal-space area $(2\pi {)}^2/A$. Counting the quantum states inside a circle givesIts derivative is the constant two-dimensional free-electron density of states. Defining $D=A{m}^{\ast }/(\pi {\hslash }^2)$, the signed-energy density of states isThe total electronic density of states is therefore $D$ on either side of zero, not $2D$ at every signed energy. If instead one counts positive-energy excitations, the electron and hole species each have density of states $D$, giving $2D$ when summed. A common additional valley degeneracy multiplies all these quantities by that factor. The effective mass approximation assumes thermally sampled energies remain within the near-edge regions of both energy bands.

The number of symmetry-related equivalent electronic valleys contributing to a specified low-energy energy band. It multiplies the single-valley density of states, independently of spin degeneracy. Equal electron and hole effective masses alone do not ensure equal total density of states values unless their valley degeneracies and spin degeneracies also agree.