Assume zero temperature, the linear Dirac cone, and both real-spin states and both electronic valleys. Define as excess Electron number per unit area, negative for an excess of electron holes, relative to neutrality. A filled circular region of radius in wave vector space contains
Thus the excess carrier density grows quadratically with the Fermi energy, unlike the constant density of states of a parabolic two-dimensional band. Differentiating gives the positive density of states per unit area, . Both the geometry of occupied states and the fourfold degeneracy matter to the coefficient.
Dirac valleys in graphene 2026-10-18
At either displayed wave vector, the three complex hopping amplitudes add to zero: . Therefore the energy bands touch. There are two inequivalent electronic valleys; other equivalent corners are related by reciprocal-lattice translations. Setting and retaining first-order terms gives
where are Pauli matrices. For example, at , . The matrix has the form of a massless two-dimensional Dirac Hamiltonian. Here is a material-model velocity, rather than the vacuum speed of light; this description does not change an Electron's vacuum rest mass. It describes the dispersion relation of electronic excitations near a band crossing.