Let the sample area be , set the band touching energy to zero, and write . Assume one electronic valley in each energy band with two spin states. The near-edge parabolic dispersions areUnder periodic boundary conditions, each spin occupies reciprocal-space area . Counting the quantum states inside a circle givesIts derivative is the constant two-dimensional free-electron density of states. Defining , the signed-energy density of states isThe total electronic density of states is therefore on either side of zero, not at every signed energy. If instead one counts positive-energy excitations, the electron and hole species each have density of states , giving when summed. A common additional valley degeneracy multiplies all these quantities by that factor. The effective mass approximation assumes thermally sampled energies remain within the near-edge regions of both energy bands.
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