For , the preceding density of states has
When , the Bose-Einstein distribution has the classical approximation
Each of the modes therefore contributes to the energy, so the Dulong-Petit law gives
When , the upper integration limit tends to infinity. The Bose integral
then yields
Hence the heat capacity at constant volume is
so . The high-temperature constant is the classical equipartition theorem result, while the low-temperature power law makes as required by the Third law of thermodynamics.
Adding to the quadratic bending energy of an elastic filament contributes to its variational derivative. The endpoint term is . If the real filament tension vanishes at both ends, the usual self-adjoint endpoint conditions for filament bending remain valid. A complete eigenfunction expansion diagonalizes the energy even when the eigenfunctions have no explicit formula. Thermal equipartition theorem arguments require positive eigenvalues after fixing any kernel; strong compression can violate this requirement.
For a positive quadratic bending operator with a real orthonormal basis of eigenfunctions, the equipartition theorem gives , where . This is the inverse-operator Green function multiplied by Boltzmann constant and temperature. Unconstrained zero-energy filament modes prevent a normalizable canonical ensemble, and negative modes signal an unstable quadratic model.
For both ends clamped and , the diagonal is . This differs from a clamped-free tip variance. The center variance is .
Zero-energy filament mode 2026-10-07
A zero-energy mode lies in the kernel of the quadratic elastic filament operator. For pure bending, zero curvature makes the displacement affine. Free-free endpoints therefore leave translation and tilt modes, while slope-constrained, force-free endpoints leave only translation. Both clamped-clamped and hinged-hinged endpoints remove these modes. An unrestricted modal amplitude has constant Boltzmann distribution weight, so no normalizable canonical ensemble or finite displacement variance exists. Fixing the rigid degrees of freedom allows the equipartition theorem on the positive complement.