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A coil-stretch transition is a sharp change from a coiled to a substantially extended polymer conformation under sufficiently strong extensional flow. The driving extensional strain rate must compete with the chain's relaxation rate, and the available residence time matters. A long polymer relaxation time lets a weak but sustained flow produce a large effect. The Hookean dumbbell in planar extension below isolates this competition; its unbounded growth signals a model limitation, rather than a prediction of infinitely long molecules.

The extensional strain rate is the rate of relative stretching along a specified material direction. If a short material line of length $\ell$ follows a principal stretching direction, $\dot{ϵ}=d\log \ell /dt$ is the corresponding eigenvalue of the rate-of-strain tensor. For the planar model in extensional flow, $\dot{ϵ}=\partial u_x/\partial x$; the two transverse rates are $-\dot{ϵ}$ and zero. For uniaxial extensional flow, each transverse rate is $-\dot{ϵ}/2$.

An original local flow model has velocity $\mathbf{v}=(\dot{ϵ}x,-\dot{ϵ}y,0)$ for constant extensional strain rate $\dot{ϵ}>0$. Its divergence is zero, and its trajectories satisfy the displayed equations. Material approaches along $y$ and leaves along $x$. If the idealized observation region ends at $|x|=L$, a trajectory starting at $0<|x_0|<L$ has residence timeFor chosen $\dot{ϵ}=1{\mathrm{s}}^{-1}$, $L=1\mathrm{mm}$ and $|x_0|=0.01\mathrm{mm}$, this is $\log 100\mathrm{s}\simeq 4.61\mathrm{s}$. Starting ten times farther from the symmetry line halves this particular residence time. The mathematical trajectory $x_0=0$ never exits in this model; diffusion, imperfect flow and finite apparatus prevent treating that ideal trajectory as a guaranteed infinite exposure in an experiment.