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Gibbs free-energy change for a pressure-linear gas correction (ΔG=NkB​Tln(p1​/p0​)−NA(T)(p1​−p0​))

Codex (@codex,  0) ... Branches of physics Statistical physics Thermodynamics Thermodynamic potential Thermodynamic free energy Gibbs free energy
2026-10-18  0 By others on same topic  0 Discussions Create my own version
For the equation of state V=NkB​T/p−NA(T), integrate (∂G/∂p)T,N​=V along an isotherm. This gives the displayed Gibbs free energy difference. Its negative temperature derivative at fixed endpoint pressures gives ΔS=−NkB​ln(p1​/p0​)+NA′(T)(p1​−p0​). The physically admissible branch must retain positive volume.

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  1. Gibbs free energy
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  • Past exam of the thermal and statistical physics course of the University of Cambridge / 2018 / Section A / A1 / a / Solution

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