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Define $r=g_2/g_1$ and let $\sigma ={\sigma }_{21}(\omega )$ be the stimulated-emission cross section, averaged over upper magnetic sublevels. The Einstein coefficients relation $g_1{B}_{12}=g_2{B}_{21}$ gives the absorption cross section ${\sigma }_{12}=r\sigma$. Assume equally populated magnetic sublevels within each energy level, a steady pump, and a monochromatic beam. The photon flux is $I/(\hslash \omega )$; define $W=\sigma I/(\hslash \omega )$ and the effective population inversion $D=N_2-r{N}_1$. Then the rate equations areThe $WD$ term includes both stimulated emission and absorption. In steady state, adding the two rate equations gives $N_1=R_2{\tau }_1$. The first equation then yieldsThe directed beam gains energy at rate $\hslash \omega WD$ per volume, giving $dI/dz=\sigma DI$ and the optical gain coefficient $\alpha =\sigma D$. At line centre, write ${\sigma }_0={\sigma }_{21}({\omega }_{21})$. ThereforeHere ${\alpha }_0$ is the small-signal optical gain coefficient and $I_s$ is the saturation intensity, at which the local optical gain is half its small-signal value. Positive optical gain requires $r{A}_{21}{\tau }_1<1$: the lower energy level must empty sufficiently quickly.

The cancellation of ${\tau }_1$ from $I_s$ is specific to this model's steady fixed pump and the fact that every upper spontaneous emission feeds the lower energy level. Adding an extra lower-state accumulation factor to $I_s$ would contradict these rate equations. Alternative conventions using the absorption cross section must replace ${\sigma }_0$ by ${\sigma }_{12}/r$ throughout. Homogeneous spectral broadening permits the whole selected ensemble to share this local saturation response.

For a closed absorbing two-level system, write $N=N_1+N_2$, let $A=1/\tau$, and use ${\sigma }_a={\sigma }_{12}$ for the absorption cross section. This differs from the stimulated-emission cross section convention in part (a). With $r=g_2/g_1$, the rate equations areAt steady state, $N_2=W_{a}N/[A+(1+1/r)W_a]$ for $W_a={\sigma }_{a}I/(\hslash \omega )$. Hence the positive absorption coefficient isFor the given sodium fine-structure transition, the statistical weights are $g_1=2$, $g_2=4$, so $r=2$ and $1+1/r=3/2$. The small-signal transmission gives the optical depthTo account for the finite decrease of intensity through the sample, integrate $dI/dz=-\kappa I$ rather than treating the stronger beam as exactly uniform. If $T=I_{\mathrm{out}}/I_{\mathrm{in}}$, this givesTaking $270\mathrm{W}{\mathrm{m}}^{-2}$ as the incident intensity and $T=0.967$,Using the photon energy $hc/\lambda$ then givesIgnoring the small variation of the stronger intensity would instead give about $1.11\times 10^{-13}{\mathrm{m}}^2$; the integrated value uses the stated transmissions more consistently. The length is not needed to eliminate $N$, but gives the check $N\simeq 9.3\times 10^{14}{\mathrm{m}}^{-3}$.

The resonant absorption cross section is of optical-wavelength-squared size, much larger than a typical atomic geometric collision area. Pressure broadening cross sections involve phase-changing interatomic encounters and need not equal hard-sphere collision areas; their numerical value depends on collision partners and speed. No precise ratio follows from the supplied data. A useful distinction is that resonant absorption involves coherent response on the optical scale, so its cross section need not resemble an chemical atom's geometric area.

For homogeneous spectral broadening, all participating chemical atoms must share the same resonance and single-atom response width. In a dilute sample dominated by natural linewidth, the weak-beam requirement isUsing the sodium atomic mass, equality occurs near $T=0.017\mathrm{K}$, so $T\ll 17\mathrm{mK}$ is a sufficient thermal condition. Spatial Zeeman energy shifts, light shifts and transit effects should also be small, the laser should address the same selected component, and the interaction should last long enough for steady populations. Uniform impact pressure broadening can also be homogeneous, but would change the width and effective cross section; it is not included in the lifetime-only numerical model.

Real sodium also has hyperfine structure and optical pumping among magnetic sublevels. The inferred ${\sigma }_a$ is the effective cross section of the stated $g_J=2J+1$ two-level system model, assuming statistical sublevel populations and no loss into unaddressed states. A measurement on a resolved, polarized closed hyperfine structure component requires its actual transition dipole moment and selection rules; a universal polarization-independent sodium cross section cannot be inferred from this simplified model. The dependence of resonant cross sections and saturation intensities on sublevel preparation is tabulated explicitly for the real sodium D lines.^[ref]

A spectral line has finite width when the emitted or absorbed field loses coherence, or when different emitters have different transition frequencies. It is useful to distinguish homogeneous spectral broadening of each emitter from inhomogeneous spectral broadening across the ensemble.

Finite lifetime and dephasing. For an upper-state population lifetime $\tau$ and a stable lower state, the radiating amplitude decays as $e^{-t/(2\tau )}$. Its Fourier spectrum is Lorentzian, with full width at half maximumMore generally, an optical coherence time $T_2$ gives $\Delta {\omega }_{\mathrm{hom}}=2/T_2$. Both level lifetimes and pure dephasing can contribute to $1/T_2$. Distinguishing population lifetime from amplitude coherence time prevents the usual factor-of-two error.

Thermal motion. To first order in velocity, $\delta \nu ={\nu }_0{v}_{\parallel }/c$. A Maxwell-Boltzmann velocity distribution therefore produces a Gaussian profile, withThis is inhomogeneous doppler broadening: different velocity classes have different resonance frequencies. A distribution of bulk velocities can add further broadening, while a common bulk velocity shifts the line.

Interactions with the surroundings. Collisions can interrupt the dipole wave phase and perturb the energy levels, producing pressure broadening and shifts. In the impact approximation, approximately exponential wave phase relaxation produces a Lorentzian contribution; its rate increases with perturber density times an appropriate velocity-averaged collision cross section. Slowly varying electric microfields can instead produce non-Lorentzian Stark profiles. Neutral perturbers, charged perturbers and resonance interactions need not produce the same line shape. These mechanisms and the Gaussian thermal limit are distinguished in NIST's atomic-spectroscopy compendium.^[ref]

Finite observation time limits coherence; transit-time broadening also occurs for particles crossing a narrow optical beam. Strong resonant excitation causes power broadening: for an ideal lifetime-limited two-level transition, $\Delta \omega =\Gamma \sqrt{1+s}$ with population decay rate $\Gamma$ and saturation parameter $s$. Unresolved fine structure, hyperfine structure, isotope components, or spatially varying Zeeman and Stark shifts may look like a single broadened feature even though several frequencies are present.

The observed spectrum is additionally convolved with the instrument response. A Gaussian Doppler contribution convolved with Lorentzian homogeneous broadening gives a Voigt profile; their full widths do not generally add in quadrature. An informative experiment varies temperature, perturber pressure and excitation intensity separately, calibrates the spectrometer response with a narrower reference, and checks optical thickness or self-absorption. Extrapolation to weak excitation and low pressure helps isolate the lifetime contribution, while a Doppler-free technique is needed if velocity spread still dominates.