Optical pumping redistributes populations among internal quantum states by selective photon absorption followed by spontaneous emission. It can prepare atoms for measurement and participate in sub-Doppler cooling.

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Optical pumping is a process used in physics and engineering to manipulate the energy states of atoms or molecules using light. It involves the absorption of photons, usually from a laser or other light source, to excite electrons in an atom from a lower energy state to a higher energy state. This process can selectively populate certain energy levels, leading to a non-equilibrium distribution of atomic or molecular states.