Spontaneous emission is radiative decay of an excited matter quantum state by emission of a photon, without an applied resonant drive. In a simple Markov decay model the excited-level population obeys . During driven control, the expected emission count is governed by ; suppressing the lossy level's population is therefore the purpose of dark-state adiabatic transfer.

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Spontaneous emission is a process by which an excited quantum system, such as an atom or a molecule, loses energy and transitions to a lower energy state without external influence. During this transition, the system emits a photon, which carries away energy and momentum. Key characteristics of spontaneous emission include: 1. **Randomness**: The process is inherently stochastic, meaning it occurs at random times and cannot be predicted exactly.