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An overdamped bead-spring model of polymer dynamics with local friction and no long-range hydrodynamic interaction. For an ideal unentangled chain of $N$ identical frictional units, the centre-of-mass diffusion coefficient is proportional to $N^{-1}$ and the longest internal relaxation time to $N^2$. A tagged segment has an intermediate-time mean-square displacement proportional to $t^{1/2}$ before ordinary whole-chain diffusion dominates. Entanglement adds constraints beyond this model.

Take downward as positive and let gravity have magnitude $g$. For a rigid sphere of density ${\rho }_p$ in otherwise stationary fluid of density ${\rho }_f$, its weight minus buoyancy is $\frac{4}{3}\pi a^3({\rho }_p-{\rho }_f)g$. At terminal velocity, this balances the Stokes drag law:This signed downward settling velocity is negative for a buoyantly rising sphere and zero for equal densities. For fixed density contrast and dynamic viscosity, the submerged weight grows as $a^3$ while linear drag at fixed speed grows as $a$; their balance gives the settling-velocity radius scaling $U_s\propto a^2$. Meanwhile,Thus doubling the radius multiplies the predicted Stokes settling speed by four and the particle Reynolds number by eight. This makes the formula useful for separating particles by size, while also providing its own check against extrapolation to large particles.

For a computed water example, take ${\rho }_f=1000\mathrm{kg}{\mathrm{m}}^{-3}$, $\mu =1.00\times 10^{-3}\mathrm{Pa}\mathrm{s}$, ${\rho }_p=2500\mathrm{kg}{\mathrm{m}}^{-3}$, $g=9.81\mathrm{m}{\mathrm{s}}^{-2}$, and $a=10.0\mu \mathrm{m}$. These are specified rounded inputs rather than a claim of exact water properties at every temperature. They giveThe diameter is $20.0\mu \mathrm{m}$, and both the net downward weight and the upward drag force are $6.16\times 10^{-11}\mathrm{N}$. At this terminal velocity, falling $1.00\mathrm{mm}$ takes $3.06\mathrm{s}$. At $a=20.0\mu \mathrm{m}$ the prediction is $1.308\mathrm{mm}{\mathrm{s}}^{-1}$ with ${\mathrm{Re}}_d=0.05232$; at $a=50.0\mu \mathrm{m}$ it is $8.175\mathrm{mm}{\mathrm{s}}^{-1}$ with ${\mathrm{Re}}_d=0.8175$, which is no longer a convincing small-Reynolds number case. The figure labels these as predictions of the Stokes settling velocity formula and shows where its inertia check fails.

The calculation describes the eventual terminal velocity, not the release transient governed by particle acceleration and possibly the Unsteady Stokes equation. Walls, hydrodynamic interactions, departures from a rigid sphere, or a different surface condition require a different resistance. For sufficiently small particles, Brownian motion can obscure individual settling trajectories; the formula still specifies the gravitational drift within its assumptions. The balancing argument already appears in article 43 of ^[ref].

A dilute-solution bead-spring model including solvent-mediated hydrodynamic interactions. In its scaling regime, a chain of size $R$ has translational diffusion coefficient of order $k_{B}T/({\eta }_{s}R)$ and longest relaxation time of order ${\eta }_s{R}^3/(k_{B}T)$. Intermediate-time segment mean-square displacements scale as $t^{2/3}$. Screening of hydrodynamic interactions in a concentrated solution changes the regime toward Rouse model behaviour; constraints from polymer entanglement require additional physics.