Hydrogenic donor state

A shallow donor impurity in an isotropic semiconductor can be approximated by an electron of effective mass $m^{\ast }$ in a Coulomb potential screened by relative permittivity ${ϵ}_r$. Its ground-state binding energy and radius areThe donor level lies $E_B$ below the conduction band. These are magnitudes: the bound electron's energy relative to the band edge is negative. Band anisotropy, short-distance impurity structure and screening by mobile carriers can invalidate the simple Bohr model rescaling.