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Departure of an intrinsic nuclear shape from spherical symmetry. Here intrinsic means referred to axes attached to a model nuclear charge distribution. A nuclear quantum state with definite spin need not have the same laboratory charge density as that intrinsic distribution. In particular, the ground state of a deformed even-even nucleus can have $I=0$, a spherical laboratory expectation value, and a nonzero intrinsic nuclear quadrupole moment.

For an illustrative uniform charge density inside a spheroid, let the semiaxes be $(a,a,c)$ and keep its volume equal to that of a sphere of radius $R$:Thus $\eta >1$ gives a prolate spheroid, $\eta =1$ a sphere, and $\eta <1$ an oblate spheroid. These are three-dimensional equal-volume shapes: equal areas of their drawn cross-sections would be a different constraint. Real nuclear charge distributions have diffuse surfaces and need not be uniform, axially symmetric or confined to one shape.

nuclear radius scaling follows approximately $R=r_0{A}^{1/3}$ with $r_0\simeq 1.2\mathrm{fm}$ for a sharp matter-radius convention. Consequently the interior nucleon density is nearly independent of mass number: nuclear forces are short range and exhibit nuclear matter saturation. A diffuse nuclear charge distribution has a charge-weighted root mean square radius, not a hard surface. For a uniform sphere, $r_{\mathrm{ch}}=\sqrt{3/5}R$; charge radii and matter radii need not coincide, especially with neutron skins.

Elastic electron scattering measures the nuclear charge form factor. In a simple one-photon, spherical approximation, with $q$ a wave number,The scattering cross section relative to a point-charge prediction is proportional to $|F{|}^2$, so its low-$q$ slope constrains the radius and diffraction structure constrains the radial distribution. Finite momentum coverage and Coulomb distortion in electron scattering limit reconstruction. In Robert Hofstadter's experiment a magnetic spectrometer separated elastic and inelastic electron peaks; beam-charge normalization and closed-slit background checks prevented raw count structure from being mistaken for a nuclear charge form factor.^[ref]

A useful intrinsic-shape description is $R(\theta ,\varphi )=R_0[1+{\sum }_{\mu =-2}^2{\alpha }_{2\mu }{Y}_{2\mu }(\theta ,\varphi )+\cdots ]$. An intrinsic nuclear quadrupole moment $Q_0=\int {\rho }_{\mathrm{ch}}(3z^2-r^2)d^{3}r$ distinguishes prolate and oblate positive-charge distributions by positive and negative signs. The laboratory spectroscopic nuclear quadrupole moment is state dependent: an $I=0$ state has zero laboratory quadrupole moment even when its intrinsic shape is deformed. nuclear rotational bands approximately follow $E_I\propto I(I+1)$; harmonic nuclear quadrupole vibrations instead have equally spaced phonon energies and multiphonon spin multiplets. Measured electric quadrupole transitions test the collective interpretation in addition to level energies. Radius probes spatial extent; quadrupole observables and collective spectra probe shape.

The laboratory expectation value of the axial electric quadrupole moment in the stretched nuclear quantum state $|I,M=I⟩$; $M\hslash$ is the laboratory $z$ component of total angular momentum. It differs from the intrinsic nuclear quadrupole moment $Q_0$. In an axial nuclear rotational band with $K=0$, projection onto definite angular momentum givesHere $K\hslash$ denotes the component of total angular momentum along the intrinsic symmetry axis. Consequently a positive $Q_0$ for a prolate spheroid corresponds to a negative $Q_s(2)$ in this model. The sign of the laboratory moment alone must be interpreted together with the band assignment.

The $I=0$ result has a short symmetry explanation. A spin-zero state has no preferred spatial direction. Its second charge moments satisfy $⟨x^2⟩=⟨y^2⟩=⟨z^2⟩$, so $⟨2z^2-x^2-y^2⟩=0$. Equivalently, averaging an intrinsic axis uniformly over directions gives $⟨P_2(\cos \theta )⟩=0$, where $P_2(u)=(3u^2-1)/2$ is a Legendre polynomial. This is a statement about a quantum expectation value, not a classical picture of a spinning object sweeping through orientations.

For an independent check of the $I=2$ sign, the $K=0$, $M=2$ rotor orientation probability is proportional to $|Y_2^2{|}^2\propto {\sin }^4\theta$, using a spherical harmonic. With $u=\cos \theta$,A zero static laboratory moment does not make every quadrupole observable zero. With electric multipole operator ${\mathcal{M}}_{2\mu }=\int {\rho }_{\mathrm{ch}}{r}^2{Y}_2^{\mu }{d}^{3}r$, define the reduced transition strength using a reduced matrix element:In the axial $K=0$ rotor, angular projection gives $B(E2;0^{+}\to 2^{+})=5Q_0^2/(16\pi )$ and $B(E2;2^{+}\to 0^{+})=Q_0^2/(16\pi )$. The factor of five is the ratio of the numbers of magnetic substates. Thus an electric quadrupole transition can reveal collective deformation even when $Q_s(0)=0$. These strengths determine $|Q_0|$ within the model; their squares alone cannot distinguish its sign.