An objective time derivative transforms covariantly under time-dependent rigid changes of observer, so constitutive predictions do not depend on the observer's rotation.
Using the component-first velocity gradient , the Rivlin-Ericksen tensors are defined by the displayed recurrence. In particular is twice the rate-of-strain tensor. These tensors transform objectively under time-dependent rigid observer changes. With this convention the upper-convected derivative of is , an identity useful in the slow-flow expansion of a second-order fluid.
With velocity gradient , set . A vector rigidly rotating with the material has material derivative , so its corotational derivative vanishes. Its unit rotational coefficient is fixed by an objective time derivative; adding describes the material's flow alignment of a polar order parameter.
For azimuthal velocity , the velocity gradient in the rotating polar basis is . The basis rotates along a particle at angular speed . Accounting for that rotation in the material derivative replaces by in the upper-convected derivative. Its remaining shear rate is , so the local viscoelastic normal-stress difference follows the same constitutive algebra as simple shear flow.
Differentiate the Kirchhoff stress tensor relation , using for the velocity gradient. Subtracting the two deformation terms gives the displayed upper-convected derivative. This removes the transport generated solely by deformation of a fixed material stress tensor.
The upper-convected Maxwell model evolves viscoelastic stress according toIt has constant shear viscosity and predicts a divergent extensional viscosity at a finite extension rate.
The Giesekus model adds the nonlinear anisotropic-drag term to the Upper-convected Maxwell model. Positive dimensionless mobility factor produces shear thinning and a nonzero second normal-stress difference.
For , the product rule proves the displayed lower-convected derivative identity. Under a superposed rotation , and . The two rotation terms in cancel those in , proving that the lower-convected rate is an objective time derivative.
If an orthogonal matrix satisfies for the spin tensor , the Jaumann derivative becomes an ordinary derivative in that frame:This follows by differentiating all three factors and using . It converts a tensor relaxation law using the Jaumann derivative into a componentwise ordinary differential equation.
The corotational Maxwell fluid replaces the ordinary derivative of the linear Maxwell fluid by the Jaumann derivative:Here uses , or equivalently the commutator is with the standard spin tensor. The stress has relaxation time and small-rate viscosity . The commutator makes the constitutive equation nonlinear while maintaining an objective time derivative.
For simple shear flow , put and . The steady deviatoric stress isThis follows by setting , in the corotational Maxwell fluid equation: , , and . Hence the shear viscosity is , which exhibits shear thinning, while and . These differences are independent of the isotropic pressure.
Use the derivative-index-first velocity gradient and . For an objective time derivative the tensor transformation under must imply . If , then andConsequently the extra terms cancel in , proving covariance. With the component-index-first gradient , the same physical rate is , with spin tensor . Changing the gradient convention without changing the commutator sign destroys objectivity.
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