For the lower-face-first ray path through an equilateral optical prism, take external entry angle , internal refraction angle , base incidence and one total internal reflection at the horizontal base. At the other sloped face the internal incidence equals , so Snell's law gives exit angle again. Its counterclockwise, oriented direction change is the displayed expression with . It is independent of refractive index for this route, but whether the base reflection is total is not. Under normal dispersion, a setting at the green critical threshold sends shorter wavelengths along the total-reflection route while longer wavelengths can leak through the base.
For a homogeneous optical prism in air, with apex angle and refractive index , minimum deviation occurs at the symmetric ray path. Then both internal angles are and both external angles are , so Snell's law gives
Measuring the deviation therefore determines the refractive index at the chosen wavelength.

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