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The laws of black-hole mechanics establish the classical analogy with thermodynamics. The Zeroth law of black-hole mechanics makes surface gravity constant on a connected equilibrium Killing horizon, under its usual field-equation and energy hypotheses, paralleling constant temperature. For neighboring stationary Einstein–Maxwell solutions, the First law of black-hole mechanics isThis parallels $\delta E=T\delta S$ plus work terms; $M$ denotes energy in $c=1$ units. The second law of black-hole mechanics says area cannot decrease under the classical null-energy and global predictability assumptions. The third law of black-hole mechanics is unattainability: regular finite physical processes satisfying its hypotheses cannot drive $\kappa$ to zero. It parallels unattainability of absolute zero, not a universal assertion of zero extremal entropy.

Classically a hole absorbs without emitting, so the analogy alone does not identify a measured temperature. Quantum Hawking radiation supplies $T_H=\hslash \kappa /(2\pi )$, with $c=k_B=1$ and future-horizon normalization at infinity. Comparing the area terms in the first laws gives the Bekenstein-Hawking entropyup to a conventionally fixed additive constant. In ordinary units it is $k_B{c}^{3}A/(4G\hslash )$. Entropy scales with area, not interior volume.

For the massless scalar in quantum field theory in curved spacetime, global hyperbolicity ensures well-posed Cauchy evolution. The conserved Klein-Gordon inner product isIts current has zero divergence by the wave equation, making it slice-independent with appropriate boundary behavior. Positive frequency relative to the asymptotic past and future Minkowski times defines complete bases $u_j,v_i$, with $(u_i,u_j)={\delta }_{ij}$, $(u_i^{\ast },u_j^{\ast })=-{\delta }_{ij}$ and vanishing mixed products. Expand the field asContinuous labels replace sums by integrals; wave packets avoid artificial normalization infinities. Particle creation by a nonstationary spacetime occurs when evolution mixes frequency signs through a Bogoliubov transformation:The inner product gives $\alpha {\alpha }^{†}-\beta {\beta }^{†}=I$ and $\alpha {\beta }^{\mathsf{T}}=\beta {\alpha }^{\mathsf{T}}$. For the initial vacuum annihilated by all $a_j^{\mathrm{in}}$, $\boxed{⟨N_i^{\mathrm{out}}{⟩}_{\mathrm{in}}=\sum _j|{\beta }_{ij}{|}^2}$. Thus nonzero negative-frequency mixing makes the in-vacuum non-vacuum for final observers. The vacuum state in a stationary spacetime depends on its positive-frequency splitting; this is not inconsistent with deterministic mode evolution. A unitary implementation on one fixed infinite-mode Fock space further needs the Hilbert–Schmidt condition on $\beta$.

For collapse forming a Schwarzschild black hole, a late outgoing ray traced back to past null infinity obeys the Hawking exponential ray mapPulling $e^{-i\omega u}$ back gives $(U_H-U{)}^{i\omega /\kappa }$ for $U<U_H$. Its past Fourier transform has both frequency signs. For $y=\omega /\kappa$ and damping $ϵ>0$, the Gamma function evaluates the Fourier integrals asAs $ϵ\downarrow 0$, the two denominator arguments approach $\mp \pi /2$, so $|I_{+}|/|I_{-}|=e^{-\pi y}$. Thus the thermal ratio of Hawking Bogoliubov coefficients is $|\beta {|}^2/|\alpha {|}^2=e^{-2\pi \omega /\kappa }$. Together with the bosonic normalization difference, this yields $1/(e^{2\pi \omega /\kappa }-1)$. Potential scattering adds a greybody factor:The collapse state has outgoing flux at future infinity without an incoming thermal bath and is regular for infall. It is not the eternal-hole equilibrium state. Horizon-entering modes complete the future basis; tracing over their correlated partners gives the approximately thermal exterior state. The collapsing geometry is not literally Minkowskian everywhere in the far future: asymptotically flat null-infinity modes are the relevant application of the earlier in/out construction.

Emission reduces the isolated hole's mass. Schwarzschild temperature is proportional to $M^{-1}$, giving the negative heat capacity of a Schwarzschild black hole: losing energy makes it hotter. Dimensional estimates give luminosity proportional to $M^{-2}$ and evaporation time proportional to $M^3$, with species and greybody factors determining coefficients. Area may shrink because quantum stress violates the energy assumptions of Hawking's area theorem. The generalized second law instead concerns $S_{\mathrm{gen}}=A/(4G\hslash )+S_{\mathrm{outside}}$, incorporating radiation entropy and preventing ordinary thermodynamic violations by disposal of entropy into a hole.

Pair correlations also distinguish thermal reduced states from the complete pure state. The black hole information paradox asks whether complete evaporation preserves quantum information: an exactly thermal final exterior with no remaining partners would appear inconsistent with unitary pure-state evolution. The semiclassical calculation controls late-time flux, not the Planck-scale endpoint, and does not itself settle this question. Quantum emission gives the temperature–entropy identification physical meaning; generalized entropy replaces the classical area alone when radiation back-reacts.